Selektive Auf- und Abbaureaktionen kationischer cyclo-Phosphane
Project leader: Prof. Jan J. Weigand
Title: Selective Formation- and Degradation Reactions of Cationic Cyclo-Phosphanes
The formation of neutral, monocyclic (poly)phosphanes (cyclo-RnPn) is well known and their chemistry is well established, whereas cationic cyclo-phosphanes with the general formula RnPnn+ are essentially unknown. As the reactivity of cyclo-phosphanes is determined by the substituents at the P atoms, the introduction of cationic charges is expected to have a tremendous influence leading to novel reaction pathways and unknown compounds. This project aims to develop new and rational approaches for the synthesis and the subsequent reactivity of cationic, cyclo-phosphanes oft he general formula RnPnn+.
Conveying period: 01.11.2019 – 28.02.2023
