Subproject C06
Table of contents
2nd Funding Period
Magnetism and Electrostatic Gradients in 2D Polymers and Their Heterostructures
The project will explore the possibility to exploit collective electronic properties, i.e., magnetism and electrostatic gradients, to develop 2DPs with unique properties. The first objective is to establish 2DPs with metal-free magnetism. As second objective they will develop stacked 2DPHSs with well-defined pore geometry and electrostatic potential gradient normal to the lattice plane, allowing for charge-selective ion flow.
1st Funding Period
Lattice-Induced Properties of 2D Framework Materials
Theproject will computationally design 2D framework materials with particular lattice topologies, explore their properties as single- and few-layer materials. It is expected that interlayer interactions depending on stacking orientation and alter the electronic properties. For the most interesting representatives computationally designed monomers able to form these lattices via state-of-the-art coupling reactions will be designed. After thorough evaluation of stability factors and formation routes it will be possible to suggest promising novel 2D framework materials to partners of research area A. Moreover, the project assist in the characterization of vibrational spectroscopy, core-hole spectroscopy, and simulation of Kelvin probe experiments.
Principal investigator
Prof. Dr. Thomas Heine