Porous materials developed at the Dresden University of Technology (DUT-n)

TUDMOF-1

Description:

Mo₃(BTC)₂

Reference:

Markus Kramer,Ulrich Schwarz and Stefan Kaskel, "Synthesis and properties of the metal-organic framework Mo₃(BTC)₂ (TUDMOF-1).",J. Mater. Chem., 2006, 16, 2245 - 2248.

Graph:

TUDMOF-2

Description:

[Mg(DMF)₂(H₂O₎₂]•2,6-ndc[Mg₃(2,6-ndc)₃(DMF)₄]

Reference:

Irena Senkovska and Stefan Kaskel, "Solvent-Induced Pore-Size Adjustment in the Metal-Organic Framework [Mg₃(ndc)₃(dmf)₄] (ndc = naphthalenedicarboxylate).",Eur. J. Inorg. Chem. 2006, 4564–4569.

Graph:

TUDMOF-3

Description:

[Mg₃(2,6-ndc₎₃(DIF)₄]
[Mg₃(2,6-ndc)₃(DMF)₂(CH₃OH)(H₂O)](DMF)

Reference:

Irena Senkovska, Julia Fritsch, and Stefan Kaskel, "New Polymorphs of Magnesium-Based Metal–Organic Frameworks Mg₃(ndc)₃ (ndc = 2,6-Naphthalenedicarboxylate).",Eur. J. Inorg. Chem. 2007, 5475–5479.

Graph:

DUT-4

Description:

Al(OH)(2,6-ndc)

Reference:

I. Senkovska; F. Hoffmann; M. Froeba; J. Getzschmann; W. Boehlmann; S. Kaskel: “New highly porous aluminum based metal-organic frameworks: Al(OH)(ndc) (ndc = 2,6-naphthalene dicarboxylate) and Al(OH)(bpdc) (bpdc = 4,4'-biphenyl dicarboxylate)”, Microporous Mesoporous Mater. 2009, 122 (1-3), 93-98.

Graph:

DUT-5

Description:

Al(OH)(bpdc)

Reference:

I. Senkovska; F. Hoffmann; M. Froeba; J. Getzschmann; W. Boehlmann; S. Kaskel: “New highly porous aluminum based metal-organic frameworks: Al(OH)(ndc) (ndc = 2,6-naphthalene dicarboxylate) and Al(OH)(bpdc) (bpdc = 4,4'-biphenyl dicarboxylate)”, Microporous Mesoporous Mater. 2009, 122 (1-3), 93-98.

Graph:

DUT-6

Description:

Zn₄O(2,6-ndc)(btb)_4/3

Reference:

N. Klein; I. Senkovska; K. Gedrich; U. Stoeck; A. Henschel; U. Mueller; S. Kaskel: “A Mesoporous Metal-Organic Framework”, Angew. Chem. Int. Ed. 2009, 48, 9954 –9957

Graph:

DUT-7

Description:

Zn₄O((S)-SpiroBIDC)₃

Reference:

Gedrich, K.; Senkovska, I.; Baburin, I. A; Mueller, U.; Trapp, O.; Kaskel, S.: “New chiral and flexible metal-organic framework with a bifunctional spiro linker and Zn₄O-nodes.”, Inorg. Chem. 2010, 49, 4440–4446

Graph:

DUT-8(Ni)

Description:

Ni₂(2,6-ndc)₂(dabco)

Reference:

N. Klein, H. C. Hoffmann, Amandine Cadiau, J. Getzschmann, M. R. Lohe, S. Paasch, T. Heydenreich, K. Adil, I. Senkovska, E. Brunner, S. Kaskel, Structural flexibility and intrinsic dynamics in the M₂(2,6-ndc)₂(dabco) (M = Ni, Cu, Co, Zn) metal–organic frameworks, J. Mater. Chem., 2012,22, 10303-10312

Graph:

DUT-9

Description:

Ni₅O₂(btb)₂

Reference:

Gedrich, K; Senkovska, I; Klein, N; Stoeck, U; Henschel, A; Lohe, MR; Baburin, IA; Mueller, U; Kaskel, S.: “A Highly Porous Metal-Organic Framework with Open Nickel Sites.", Angew. Chem. Int. Ed. 2010 49 (45), 8489-8492

Graph:

DUT-10(Zn)

Description:

Zn₂(H₂O)₂(BenzTB)
Zn= Cu, Co, Zn

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Klausch, A; Baburin, IA; Mueller, U; Kaskel, S.: “Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand", Europ. J. Inorg Chem. 2010 (24), 3835-3841.

Graph:

DUT-10(Cu)

Description:

Cu₂(H2O)₂(BenzTB)
Cu= Cu, Co, Zn

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Klausch, A; Baburin, IA; Mueller, U; Kaskel, S.: “Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand", Europ. J. Inorg Chem. 2010 (24), 3835-3841.

Graph:

DUT-10(Co)

Description:

Co₂(H2O)₂(BenzTB)
Co= Cu, Co, Zn

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Klausch, A; Baburin, IA; Mueller, U; Kaskel, S.: “Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand", Europ. J. Inorg Chem. 2010 (24), 3835-3841.

Graph:

DUT-11

Description:

Zn₂(H₂O)₂(BenzTB)

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Klausch, A; Baburin, IA; Mueller, U; Kaskel, S.: “Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand", Europ. J. Inorg Chem. 2010 (24), 3835-3841.

Graph:

DUT-12

Description:

Cu₂(H₂O)₂(BenzTB)

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Klausch, A; Baburin, IA; Mueller, U; Kaskel, S.: “Topological Diversity, Adsorption and Fluorescence Properties of MOFs Based on a Tetracarboxylate Ligand", Europ. J. Inorg Chem. 2010 (24), 3835-3841.

Graph:

DUT-13

Description:

Zn₄O(BenzTB)_3/2

Reference:

Grunker, R; Senkovska, I; Biedermann, R; Klein, N; Lohe, MR; Muller, P; Kaskel, S.: “A highly porous flexible Metal-Organic Framework with corundum topology.”, Chem. Comm. 2011, 47 (1), 490-492.

Graph:

DUT-14

Description:

cubic ordered mesoporous silicon carbide

Reference:

P. Krawiec, C. Schrage, E. Kockrick, S. Kaskel, "Tubular and Rodlike Ordered Mesoporous Silicon (Oxy)carbide Ceramics and their Structural Transformations.", Chem. Mater. 2008, 20, 5421-5433.

Graph:

DUT-15

Description:

cubic ordered mesoporous silicon carbide

Reference:

P. Krawiec, C. Schrage, E. Kockrick, S. Kaskel, "Tubular and Rodlike Ordered Mesoporous Silicon (Oxy)carbide Ceramics and their Structural Transformations.", Chem. Mater. 2008, 20, 5421-5433.

Graph:

DUT-16

Description:

Hexagonally ordered mesoporous boron carbide

Reference:

Borchardt L., Kockrick E., Wollmann P., Guron M., Geiger D., Sneddon L., Kaskel S., "Ordered Mesoporous Boron Carbide Based Materials via Precursor Nanocasting.", Chem. Mater. 2010, 22, (16), 4660-4668.

Graph:

DUT-17

Description:

cubic ordered mesoporous boron carbide

Reference:

Borchardt L., Kockrick E., Wollmann P., Guron M., Geiger D., Sneddon L., Kaskel S., "Ordered Mesoporous Boron Carbide Based Materials via Precursor Nanocasting.", Chem. Mater. 2010, 22, (16), 4660-4668.

Graph:

DUT-18

Description:

Hexagonally ordered mesoporous carbide derived carbon (OM-CDC)

Reference:

P. Krawiec, E. Kockrick, L. Borchardt, S. Kaskel, A. Corma, "Ordered Mesoporous Carbide Derived Carbons: Novel Materials for Catalysis and Adsorption.", J. Phys. Chem. C. 2009, 113, 7755-7761.

Graph:

DUT-19

Description:

Kubisch geordnerter mesoporöser karbidabgeleiteter Kohlenstoff (OM-CDC)

Reference:

Oschatz M., Kockrick E., Rose M., Borchardt L., Klein N., Senkovska I., Freudenberg T., Korenblit Y., Yushin G., Kaskel S., "A cubic ordered, mesoporous carbide-derived carbon for gas and energy storage applications.", Carbon 48 (14) (2010), 3987-3992.

Graph:

DUT-20

Description:

EOF-1 (Element–Organic Frameworks)

Reference:

M. Rose, W. Böhlmann, M. Sabo, S. Kaskel, "Element–organic frameworks with high permanent porosity.", Chem. Commun. 2008, 2462-2464.

Graph:

DUT-21(Si)

Description:

EOF-2 (Element–Organic Frameworks)

Reference:

M. Rose, W. Böhlmann, M. Sabo, S. Kaskel, "Element–organic frameworks with high permanent porosity.", Chem. Commun. 2008, 2462-2464.

Graph:

DUT-21(Sn)

Description:

EOF-3 (Element–Organic Frameworks)

Reference:

J. Fritsch, M. Rose, P. Wollmann, W. Böhlmann, S. Kaskel, "New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity.", Materials 2010, 3, 2447-2462.

Graph:

DUT-22(Bi)

Description:

EOF-4 (Element–Organic Frameworks)

Reference:

J. Fritsch, M. Rose, P. Wollmann, W. Böhlmann, S. Kaskel, "New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity.", Materials 2010, 3, 2447-2462.

Graph:

DUT-22(Sb)

Description:

EOF-5 (Element–Organic Frameworks)

Reference:

J. Fritsch, M. Rose, P. Wollmann, W. Böhlmann, S. Kaskel, "New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity.", Materials 2010, 3, 2447-2462.

Graph:

DUT-23

Description:

[M₂(bipy)]₃(btb)₄(DUT-23(M), M=Zn, Co, Cu, Ni)

Reference:

N. Klein, I. Senkovska, I. A. Baburin, R. Grünker, U. Stoeck, M. Schlichtenmayer, B. Streppel, U. Mueller, S. Leoni, M. Hirscher, S. Kaskel, "Route to a Family of Robust, Non-interpenetrated Metal–Organic Frameworks with pto-like Topology.", Chemistry Europ. J. 2011, 17 (46), 13007-13016.

Graph:

DUT-24

Description:

[M₂(bipy)]₃(btb)₄(DUT-23(M), M=Zn, Co, Cu, Ni)

Reference:

N. Klein, I. Senkovska, I. A. Baburin, R. Grünker, U. Stoeck, M. Schlichtenmayer, B. Streppel, U. Mueller, S. Leoni, M. Hirscher, S. Kaskel, "Route to a Family of Robust, Non-interpenetrated Metal–Organic Frameworks with pto-like Topology.", Chemistry Europ. J. 2011, 17 (46), 13007-13016.

Graph:

DUT-25

Description:

[Zn₄O(benztb)(btb)_2/3]

Reference:

R. Grunker, V. Bon, A. Heerwig, N. Klein, P. Muller, U. Stoeck, I. A. Baburin, U. Mueller, I. Senkovska and S. Kaskel, "Dye Encapsulation Inside a New Mesoporous Metal–Organic Framework for Multifunctional Solvatochromic-Response Function.", Chemistry Europ. J. 2012, 18, 13299-13303.

Graph:

DUT-27

Description:

Co₂(BTB)(NO₃)(DEF)₃(H₂O)₂

Reference:

P. Wollmann, M. Leistner, U. Stoeck, R. Grunker, K. Gedrich, N. Klein, O. Throl, W. Grahlert, I. Senkovska, F. Dreisbach, S. Kaskel, "High-throughput screening: speeding up porous materials discovery.", Chem. Commun. 2011, 47, 5151-5153.

Graph:

DUT-28

Description:

Co₂₂(BTB)₁₂(NO₃)₈

Reference:

. Wollmann, M. Leistner, U. Stoeck, R. Grunker, K. Gedrich, N. Klein, O. Throl, W. Grahlert, I. Senkovska, F. Dreisbach, S. Kaskel, "High-throughput screening: speeding up porous materials discovery.", Chem. Commun. 2011, 47, 5151-5153.

Graph:

DUT-30

Description:

Zn₂(adb)₂(dabco)
adb = 9,10-anthracene dibenzoate,
dabco =1,4-diazabicyclo[2.2.2]octane

Reference:

I. M. Hauptvogel, R. Biedermann, N. Klein, I. Senkovska, A. Cadiau, D. Wallacher, R. Feyerherm, S. Kaskel, "Flexible and Hydrophobic Zn-Based Metal–Organic Framework.", Inorg. Chem. 2011, 50, 8367-8374.

Graph:

DUT-32

Description:
Zn₄O(bpdc)(btctb)_4/3
bpdc²⁻ - 4,4′-biphenylenedicarboxylic acid
btctb³⁻ - 4,4′,4′′-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate

Reference:
Gruenker, R.; Bon V.; Mueller P.; Stoeck U.; Krause S.; Mueller U.; Senkovska I.; Kaskel S.: “A new metal-organic framework with ultra-high surface area”, Chem. Commun. (Cambridge, U. K.) (2014), 50, 3450-3452

DUT-33

Description:

[Cu₂(py)_1.5(H₂O)_0.5]₃(btb)₄ (py = pyridine)

Reference:

N. Klein, I. Senkovska, I. A. Baburin, R. Grünker, U. Stoeck, M. Schlichtenmayer, B. Streppel, U. Mueller, S. Leoni, M. Hirscher, S. Kaskel, "Route to a Family of Robust, Non-interpenetrated Metal–Organic Frameworks with pto-like Topology.", Chemistry Europ. J. 2011, 17 (46), 13007-13016.

Graph:

DUT-34

Description:

[Cu₂(H₂O)₂]₃(btb)₄

Reference:

N. Klein, I. Senkovska, I. A. Baburin, R. Grünker, U. Stoeck, M. Schlichtenmayer, B. Streppel, U. Mueller, S. Leoni, M. Hirscher, S. Kaskel, "Route to a Family of Robust, Non-interpenetrated Metal–Organic Frameworks with pto-like Topology.", Chemistry Europ. J. 2011, 17 (46), 13007-13016.

Graph:

DUT-37

Description:

[Rh(TNPS)](BF₄)
TNPS = 4-(7-norbornadienyl)phenyl)silane

Reference:

U. Stoeck, G. Nickerl, U. Burkhardt, I. Senkovska and S. Kaskel, "Modular Construction of a Porous Organometallic Network Based on Rhodium Olefin Complexation.", J. Am. Chem. Soc. 2012, 134, 17335-17337.

Graph:

DUT-40

Description:

Zn₂(H_²O)₂(BBC)](NO3)(DEF)₆
(BBC - 4,4',4''-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate)

Reference:

I. M. Hauptvogel, V. Bon, R. Grunker, I. A. Baburin, I. Senkovska, U. Mueller, S. Kaskel, "A family of 2D and 3D coordination polymers involving a trigonal tritopic linker.", Dalton Trans. 2012, 41, 4172-4179.

Graph:

DUT-41

Description:

Zn₃(H₂O)₃(BBC)₂
(BBC - 4,4',4''-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate

Reference:

I. M. Hauptvogel, V. Bon, R. Grunker, I. A. Baburin, I. Senkovska, U. Mueller, S. Kaskel, "A family of 2D and 3D coordination polymers involving a trigonal tritopic linker.", Dalton Trans. 2012, 41, 4172-4179.

Graph:

DUT-42

Description:

[(C₂H₅)₂NH₂][Zn₂(BBC)(TDC)](DEF)₆(H2O)₇
(TDC - 2,5-thiophenedicarboxylate)

Reference:

I. M. Hauptvogel, V. Bon, R. Grunker, I. A. Baburin, I. Senkovska, U. Mueller, S. Kaskel, "A family of 2D and 3D coordination polymers involving a trigonal tritopic linker.", Dalton Trans. 2012, 41, 4172-4179.

Graph:

DUT-43

Description:

Zn₁₀(BBC)₅(BPDC)₂(H₂O)₁₀(NO₃)
(BPDC - 4,4´-biphenyldicarboxylate)

Reference:

I. M. Hauptvogel, V. Bon, R. Grunker, I. A. Baburin, I. Senkovska, U. Mueller, S. Kaskel, "A family of 2D and 3D coordination polymers involving a trigonal tritopic linker.", Dalton Trans. 2012, 41, 4172-4179.

Graph:

DUT-44

Description:

Co₂(BBC)(NO₃)(DEF)₂(H₂O)

Reference:

I. M. Hauptvogel, V. Bon, R. Grunker, I. A. Baburin, I. Senkovska, U. Mueller, S. Kaskel, "A family of 2D and 3D coordination polymers involving a trigonal tritopic linker.", Dalton Trans. 2012, 41, 4172-4179.

Graph:

DUT-49

Description:

[Cu₂(BBCDC)]
(BBCDC - 9,9‘ -([1,1‘- biphenyl]-4,4‘-diyl)bis(9H- carbazole-3,6-di carboxylate)

Reference:

U. Stoeck, S. Krause, V. Bon, I. Senkovska and S. Kaskel, "A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake.", Chem. Commun. 2012, 48, 10841-10843.

Graph:

DUT-51

Description:

Zr₆O₆(OH)₂(DTTDC)₄(BC)₂(DMF)₆
(DTTDC - dithieno[3,2-b;2',3'-d]thiophene-2,6-dicarboxylate BC = benzoic acid)

Reference:

V. Bon, V. Senkovskyy, I. Senkovska and S. Kaskel, "Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology.",Chem. Commun. 2012, 48, 8407-8409.

Graph:

DUT-52

Description:
{Zr, Hf}₆O₄(OH)₄(ndc)₆
ndc^2-- 2,6-naphthalenedicarboxylate

Reference:
Bon, V.; Senkovska, I., Weiss, M. S.; Kaskel, S.: “Tailoring of network dimensionality and porosity adjustment in Zr- and Hf-based MOFs”, CrystEngComm (2013), 15, 9572-9577.

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DUT-53

Description:
Hf₆O₆(OH)₂(ndc)₄(CH₃COO)₂(Solvent)₆
ndc^2-- 2,6-naphthalenedicarboxylate

Reference:
Bon, V.; Senkovska, I., Weiss, M. S.; Kaskel, S.: “Tailoring of network dimensionality and porosity adjustment in Zr- and Hf-based MOFs”, CrystEngComm (2013), 15, 9572-9577.

DUT-58

Description:

Co₃(1,3-bib)(4,4’-bpdc)₃
(1,3-bib - 1,3-bis(imidazol-1-yl)benzene;
4,4’-bpdc - 4,4'-biphenyldicarboxylate)

Reference:

L. Schlechte, V. Bon, R. Grünker, N. Klein, I. Senkovska, S. Kaskel, "Structural diversity of cobalt(II) coordination compounds involving bent imidazole ligand: A route from 0D dimer to 3D coordination polymer.", Polyhedron 2012, 44, 179-186.

Graph:

DUT-63

Description :
Cu₃(tcbpa)₂(H₂O)₃
tcbpa – tris((4-carboxyl)phenylduryl)amine

Reference:
Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M. S.; Feng, X.; Kaskel, Stefan: “Topological control of 3,4-connected frameworks based on the Cu₂-paddle-wheel node: tbo or pto, and why?”, CrystEngComm (2016), 18(42), 8164-8171

DUT-64

Description:
Cu₂(tcbpa)_4/3
tcbpa – tris((4-carboxyl)phenylduryl)amine

Reference:
Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M. S.; Feng, X.; Kaskel, Stefan: “Topological control of 3,4-connected frameworks based on the Cu₂-paddle-wheel node: tbo or pto, and why?”, CrystEngComm (2016), 18(42), 8164-8171

DUT-67

Description:
{Zr,Hf}₆O₆(OH)₂(tdc)₄(CH3COO)_2,M = Zr, Hf
tdc^2- - 2,5-thiophenedicarboxylate

Reference:
Bon, V.; Senkovska, I.; Baburin, I. A.; Kaskel, S.: “Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism”, Cryst. Growth Des. (2013), 13(3), 1231-1237

DUT-68

Description:
{Zr,Hf}₆O₆(OH)₂(tdc)_4.5(Ac)
tdc^2- - 2,5-thiophenedicarboxylate
Ac – CH₃COO^-

Reference:
Bon, V.; Senkovska, I.; Baburin, I. A.; Kaskel, S.: “Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism”, Cryst. Growth Des. (2013), 13(3), 1231-1237

DUT-69

Description:
{Zr,Hf}₆O₄(OH)₄(tdc)₅(Ac)₂
tdc^2- - 2,5-thiophenedicarboxylate
Ac – CH3COO^-

Reference:
Bon, V.; Senkovska, I.; Baburin, I. A.; Kaskel, S.: “Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism”, Cryst. Growth Des. (2013), 13(3), 1231-1237

DUT-71

Description:
{Zr,Hf}₆O₄(OH)₄(tdc)₅(Ac)₂
tdc^2- - 2,5-thiophenedicarboxylate
Ac – CH3COO^-

Reference:
Bon, V.; Senkovska, I.; Baburin, I. A.; Kaskel, S.: “Zr- and Hf-Based Metal-Organic Frameworks: Tracking Down the Polymorphism”, Cryst. Growth Des. (2013), 13(3), 1231-1237

DUT-72

Description:
Cu₄(mpbatb)₂(dabco)_3.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.

DUT-73(a.b)

Description:
DUT-73
a: Cu₄(mpbatb)₂(1,3-bib)_0.5
b: Cu₄(mpbatb)₂(1,4-bib)_0.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate
1,3-bib - 1,3-bis(1H-imidazol-1-yl)-benzene

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.

DUT-74

Description:
Cu₄(mpbatb)₂(bpta)_0.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate
bpta - 3,6-di(4-pyridyl)-1,2,4,5-tetrazine

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.

DUT-75

Description:
Cu₃(CPCDC)₂
CPCDC^3- - 9-(4-carboxyphenyl)-9H-carbazole-3,6-dicarboxylate

Reference:
Stoeck, U.; Senkovska, I.; Bon, V.; Krause, S.; Kaskel, S.: “Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery”, Chem. Commun. (Cambridge, U. K.) (2015), 51(6), 1046-1049

DUT-76

Description:
Cu₃(CBCDC)₂
CBCDC^3- - 9-(4'-carboxy-[1,1'-biphenyl]-4-yl)-9H-carbazole-3,6-dicarboxylate

Reference:
Stoeck, U.; Senkovska, I.; Bon, V.; Krause, S.; Kaskel, S.: “Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery”, Chem. Commun. (Cambridge, U. K.) (2015), 51(6), 1046-1049

DUT-77

Description:
Cu₂(hmbqa)_4/3
hmbqa^3- – 4,4′,4″-(4,4,8,8,12,12-hexamethyl-8,12- dihydro-4H-benzoĳ9,1]quino-lizinoĳ3,4,5,6,7-defg]acridine- 2,6,10-triyl)tribenzoate

Reference:
Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M. S.; Feng, X.; Kaskel, Stefan: “Topological control of 3,4-connected frameworks based on the Cu₂-paddle-wheel node: tbo or pto, and why?”, CrystEngComm (2016), 18(42), 8164-8171

DUT-78

Description:
Cu₂(tcbpa)_4/3(Cu(salen))
tcbpa – tris((4-carboxyl)phenylduryl)amine

Reference:
Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M. S.; Feng, X.; Kaskel, Stefan: “Topological control of 3,4-connected frameworks based on the Cu₂-paddle-wheel node: tbo or pto, and why?”, CrystEngComm (2016), 18(42), 8164-8171

DUT-79

Description:
Cu₂ (hmbqa)_4/3(Cu(salen))
hmbqa^3- – 4,4′,4″-(4,4,8,8,12,12-hexamethyl-8,12- dihydro-4H-benzoĳ9,1]quino-lizinoĳ3,4,5,6,7-defg]acridine- 2,6,10-triyl)tribenzoate

Reference:
Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M. S.; Feng, X.; Kaskel, Stefan: “Topological control of 3,4-connected frameworks based on the Cu₂-paddle-wheel node: tbo or pto, and why?”, CrystEngComm (2016), 18(42), 8164-8171

DUT-80

Description:
Zr₆O₂(OH)₆(CDC)₄(HCOO)₄(CH₃COO)₂
CDC^2- – 9H-carbazole-3,6-dicarboxylate

Reference:
Krause, S.; Bon, V.; Stoeck, U.; Senkovska, I.; Többens, D. M.; Wallacher, D.; Kaskel, S.: “A Stimuli‐Responsive Zirconium Metal–Organic Framework Based on Supermolecular Design”, Angew. Chem. (2017), 129 (36), 10816-10820(5)

DUT-82

Description:
RhBTC
BTC^3- – benzene-1,3,5-tricarboxylate

Reference:
Nickerl G.; Stoeck U.; Burkhardt U.; Senkovska I.; Kaskel S.: “ A catalytically active porous coordination polymer based on a dinuclear rhodium paddle-wheel unit”, J. Mater. Chem. A, (2013), 2, 144-148

DUT-83

Description:
RhBTB
BTB^3- – benzene-1,3,5-tribenzoate

Reference:
Nickerl G.; Stoeck U.; Burkhardt U.; Senkovska I.; Kaskel S.: “ A catalytically active porous coordination polymer based on a dinuclear rhodium paddle-wheel unit”, J. Mater. Chem. A, (2013), 2, 144-148

DUT-84

Description:
Zr₆O₈(ndc)₃(CH₃COO)₂(C₂H₅OH)₇(DMF)
ndc^2-- 2,6-naphthalenedicarboxylate

Reference:
Bon, V.; Senkovska, I., Weiss, M. S.; Kaskel, S.: “Tailoring of network dimensionality and porosity adjustment in Zr- and Hf-based MOFs”, CrystEngComm (2013), 15, 9572-9577.

DUT-90

Description:
Cu₄(mpbatb)₂(1,3-bib)_0.5(dabco)_2.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate
1,3-bib - 1,3-bis(1H-imidazol-1-yl)-benzene

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.

DUT-91

Description:
Cu₄(mpbatb)₂(1,4-bib)_0.5(dabco)_2.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate
1,4-bib - 1,4-bis(1H-imidazol-1-yl)-benzene

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.

DUT-95

Description:
Cu₄(mpbatb)₂(bpta)_0.5(dabco)_2.5
mpbatb^4- - 4,4′,4″,4‴-(1,3-Phenylenebis(azanetriyl))tetrabenzoate
bpta - 3,6-di(4-pyridyl)-1,2,4,5-tetrazine

Reference:
Mueller, P.; Wisser, F. M.; Bon, V.; Gruenker, R.; Senkovska, I.; Kaskel, S.: “Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs”, Chem. Mater. (2015), 27(7), 2460-2467.