Publikationen

Das Titelbild zeigt das Spiro-Dicuban Bi7S85+ in der Mitte, begleitet von zwei Bi4S44+ Heterocubanen auf beiden Seiten, die entlang ihrer Dreifachachse dargestellt sind. Diese Sulfidobismut-Polykationen wurden in Salzen mit [AlCl4]- und [S(AlCl3)3]2- Anio

Die abschließenden Forschungsergebnisse des Schwerpunkprogramms 1708 sind als Sonderheft des Open-Source-Fachjournals ChemistryOpen (2021) erschienen.

Publikationen der zweiten Förderperiode (2017 – 2020)

Molekulares Design von und Röntgenspektroskopie an Nanocluster-Katalysatoren

Stereoselective Alkyne Hydrogenation by using a Simple Iron Catalyst
B. J. Gregori, F. Schwarzhuber, S. Pöllath, J. Zweck, L. Fritsch, R. Schoch, M. Bauer, A. Jacobi von Wangelin,
ChemSusChem, 2019, 12, 3864–3870.

Bimetallic Co/Al nanoparticles in an ionic liquid: synthesis and application in alkyne hydrogenation
L. Schmolke, B. J. Gregori, B. Giesen, A. Schmitz, J. Barthel, L. Staiger, R. A. Fischer, A. Jacobi von Wangelin, C. Janiak,
New J. Chem., 2019, 43, 16583–16594.

Nanostrukturen unedler Metalle durch Synthese in Ionischen Flüssigkeiten (BaseMet-IL)

Ge–Fe Carbonyl cluster compounds: Ionic-liquid-based synthesis, structures, and properties 
S. Wolf, A. Egeberg, J. Treptow, C. Feldmann 
Chem. Open, 2021, 10, 171-180.
[BMIm]2[Mn(CO)3(GeI3)3]: Carbonyl compound with a MnGe3 cluster  
S. Wolf, S. Wei, W. Klopper, S. Dehnen, C. Feldmann 
Inorg. Chem., 2020, 59, 12895–12902.
Ionic-Liquid-Based synthesis of GaN nanoparticles 
H. F. Gaiser, R. Popescu, D. Gerthsen, C. Feldmann
Chem. Commun., 2020, 56, 2312–2315.
[SnI8{Fe(CO)4}4]2+: eine hochkoordinierte Sn+III8 Baueinheit mit fragilen Carbonylklammern 
S. Wolf, R. Köppe, T. Block, R. Pöttgen, P. W. Roesky, C. Feldmann
Angew. Chem., 2020, 132, 5552–5556. 
[SnI8{Fe(CO)4}4]2+: Highly-coordinated Sn+III8 subunit with fragile carbonyl clips 
Angew. Chem. Int. Ed., 2020, 59, 5510–5514.
Ionic-Liquid-Based synthesis of Tellurium-Rhenium carbonyls with specific reaction control  
S. Wolf, C. Feldmann   
Dalton Trans. 2019, 48, 15521–15528.
Y3Al5O12: Ce Nanoparticles made by ionic-liquid-assisted particle formation and LiCl-matrix-treated crystallization
H. F. Gaiser, A. Kuzmanoski, C. Feldmann
RSC Adv., 2019, 9, 10195–10200.
[Pb{Mn(CO)5}3][AlCl4]: A lead-manganese carbonyl with AlCl4-linked PbMn3 clusters 
S. Wolf, D. Fenske, W. Klopper, C. Feldmann
Dalton Trans., 2019, 48, 4696–4701.
The bromine-rich Bromido metallates [BMIm]2[SnBr6]×(Br2) and [MnBr(18-crown-6)]4[SnBr6]2×(Br2)4.5 
A. Eich, R. Köppe, P. W. Roesky, C. Feldmann
Europ. J. Inorg. Chem., 2019, 9, 1292–1298.

Ge12{Fe(CO)3}8(µ-I)4: a germanium–iron cluster with Ge4, Ge2 and Ge units
S. Wolf, W. Klopper, C. Feldmann,
Chem. Commun., 2018, 54, 1217–1220.

Ionic-Liquid-based Synthesis of the Bromine-rich Platinum Bromides [NBu3Me]2[Pt2Br10](Br2)2 and [NBu3Me]2[Pt2Br10](Br2)3
A. Eich, R. Köppe, P. W. Roesky, C. Feldmann,
Z. Anorg. Allg. Chem., 2018, 644, 275–279.

The Mixed Valence Iodine Chlorides [PCl4]2[ICl2][ICl4] and [BnMe3N]2[I2Cl3][ICl4]
D. Hausmann, A. Eich, C. Feldmann,
J. Mol. Struct., 2018, 1166, 159–163.

Bimetallic Nickel-Iridium and Nickel-Osmium Alloy Nanoparticles and Their Catalytic Performance in Hydrogenation Reactions
A. Egeberg, C. Dietrich, C. Kind, R. Popescu, D. Gerthsen, S. Behrens, C. Feldmann,
ChemCatChem, 2017, 9, 3534–3543.

Ionic-Liquid-Based Synthesis of the Germanium-Iron Carbonyls FeI4{GeI3Fe(CO)3}2 and (GeI3)2Fe(CO)4
S. Wolf, C. Feldmann,
Z. Anorg. Allg. Chem., 2017, 643, 25–30.
Comparing the luminescence of YVO4:Eu and core-shell YVO4@YF3 nanocrystals with Bulk-YVO4:Eu 
L. Shirmane, C. Feldmann, V. Pankratov 
Physica B, 2017, 504, 80–85.
Energy transfer of the Quantum-Cutter Couple Pr3+–Mn2+ in CaF2:Pr3+,Mn2+ nanoparticles
A. Kuzmanoski, V. Pankratov, C. Feldmann 
J. Lumin., 2016, 179, 555–561.
MnBr2/(18-crown-6) Coordination complexes showing high room temperature luminescence and quantum yield 
D. Hausmann, A. Kuzmanoski, C. Feldmann
Dalton Trans., 2016, 45, 6541–6547.
The bromine-rich zinc bromides Zn6Br12(18-crown-6)2(Br2)5, Zn4Br8(18-crown-6)2(Br2)3 and Zn6Br12(18-crown-6)2(Br2)2   
D. Hausmann, C, Feldmann 
Inorg. Chem., 2016, 55, 6141–6147.
Ionic-liquid-assisted synthesis of the phosphorus interhalides [PBr4][IBr2] and [PBr4][I5Br7] 
D. Hausmann, R. Köppe, S. Wolf, P. W. Roesky, C. Feldmann
Dalton Trans., 2016, 45, 16526–16532.

Tieftemperatur-Umwandlungen von komplexen festen Präkursoren in ionischen Flüssigkeiten: Neue Verbindungen und Einsichten in Reaktionsprinzipien

Low Temperature Activation of Tellurium and Resource-Efficient Synthesis of AuTe2 and Ag2Te in Ionic Liquids
Grasser, M. A., Pietsch, T. Brunner, E., Doert, T., Ruck, M.
Chem. Open, 2021, 10 (2), 117-124.
Noble Metal Assisted Synthesis of Cationic Sulfidobismuth Cubanes in Ionic Liquids
Knies, M., Groh, M.,Pietsch, T., Lê Anh, M., Ruck M.
Chem. Open, 2021, 10 (2), 59.
One-pot resource-efficient synthesis of SnSb powders for composite anodes in sodium-ion batteries
Tan, D., Chen, P., Wang, G., Chen, G.B., Pietsch, T., Brunner, E., Doert, T., Ruck, M.
RSC Adv., 2020, 10, 22250 – 22256.
Resource‐Efficient Low‐Temperature Synthesis of Microcrystalline Pb2B5O9X (X = Cl, Br) for Surfaces Studies by Optical Second Harmonic Generation
Tan, D., Kirbus, B., Rüsing, M., Pietsch, T., Ruck, M., Eng, L. M.
Small, 2020, 16 (23), 2000857.
Low-Temperature Ionothermal Synthesis of Li-Ion Conductive Li4B7O12Cl Solid-State Electrolyte
Tan, D., Wang, F., Pietsch, T., Grasser, M. A., Doert, T., Ruck, M.
ACS Appl. Energy Mater., 2019, 2 (7), 5140–5145.

Low-Temperature Ordering in the Cluster Compound (Bi8)Tl[AlCl4]3
M. Knies, M. Kaiser, M. Lê Anh, A. Efimova, Th. Doert, M. Ruck,
Inorganics, 2019, 7 (4), 45.

Spontaneous Substitutions on Phosphorus Trihalides in Imidazolium Halide Ionic Liquids: A Grotthuss Diffusion of Anions?
O. Holloczki, A. Wolff, J. Pallmann, R. Whiteside, J. Hartley, M. A. Grasser, P. Nockemann, E. Brunner, Th. Doert, M. Ruck,
Chem. Eur. J., 2018, 16323–16331.

Low-temperature tailoring of copper-deficient Cu3-xP – electric properties, phase transitions and performance in Li ion batteries
A. Wolff, T. Doert, J. Hunger, M. Kaiser, J. Pallmann, R. Reinhold, S. Yogendra, L. Giebeler, J. Sichelschmidt, W. Schnelle, R. Whiteside, H.Q. N. Gunaratne, P. Nockemann, J. Weigand, E. Brunner, M. Ruck,
Chem.Mater., 2018, 7111–7123.

The Intermetalloid Cluster Cation (CuBi8)3+
M. Knies, M. Kaiser, A. Isaeva, U. Müller, T. Doert, M. Ruck,
Chem. Eur. J., 2018, 24, 127–132.

Understanding the Chemical Reactivity of Phosphonium-Based Ionic Liquids with Tellurium
T. Zhang, K. Schwedtmann, J. Weigand, T. Doert, M. Ruck,
Chem. Eur. J., 2018, 24, 9325–9332.

Mechanistic exploration of the copper(I) phosphide synthesis in phosphonium-based and phosphorus-free ionic liquids
M. Lê Anh, A. Wolff, M. Kaiser, S. Yogendra, J. Weigand, J. Pallmann, E. Brunner, M. Ruck, T. Doert,
Dalton Trans., 2017, 46, 15004–15011.

Dissolution behaviour and activation of selenium in phosphonium based ionic liquids
T. Zhang, K. Schwedtmann, J. Weigand, T. Doert, M. Ruck,
Chem. Commun., 2017, 53, 7588–7591.

On the Anion Exchange of PX3 (X = Cl, Br, I) in Ionic Liquids comprising Halide Anions
A. Wolff, J. Pallmann, E. Brunner, T. Doert, M. Ruck,
Z. Anorg. Allg. Chem., 2017, 643, 20–24.

Synthese intermetallischer Phasen in ionischen Flüssigkeiten

Reactivity and Controlled Redox Reactions of Salt-like Intermetallic Compounds in Imidazolium-based Ionic Liquids
X.-J. Feng, S. Lerch, H. Biller, M. Micksch, M. Schmidt, M. Baitinger, Th. Strassner, Y. Grin, B. Böhme,
Chem. Open, 2021, 10, 205 –215.
An Electrochemical Approach toward the Metastable Type II Clathrate Germanium Allotrope
B. Böhme,
Inorg. Chem., 2020, 59/17, 11920–11924.
Synthesis of plasmonic Fe/Al nanoparticles in ionic liquids
A. Schmitz, H. Meyer, M. Meischein, A. Garzón Manjón, L. Schmolke, B. Giesen, C. Schlüsener, P. Simon, Y. Grin, R. A. Fischer, C. Scheu, A. Ludwig, C. Janiak
RSC Adv.,  2020, 10, 12891–12899.

Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Nanoscale, 2019, 11, 4073–4082.

Niedertemperatur-Zugang zu Solvensfreien Chalkogenidometall- Materialien

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles
B. Peters, S. Santner, C. Donsbach, P. Vöpel, B. Smarsly, S. Dehnen,
Chem. Sci., 2019, 10, 5211–5217.
(Inside Front Cover)
Highlights: www.chemie.de, ChemSci Pick of the Week

Current Advances in Tin Cluster Chemistry
B. Peters, N. Lichtenberger, E. Dornsiepen, S. Dehnen,
Chem. Sci., 2020, 11, 16−26 (Perspective Article).
Highlight: Part of the 2019 Chemical Science HOT Article Collection).

A Methylated Oxo-Thio Stannate Cluster from a Non-Innocent Ionic Liquid
B. Peters, S. Reith, S. Dehnen,
Z. Anorg. Allg. Chem., 2020, 646, 964–947. 

Dimensional reduction of a selenido stannate salt in ionic liquids to form a direct heavy homologue of an oxo silicate
B. Peters, S. Santner, S. Dehnen,
Z. Anorg. Allg. Chem., 2020, 646, in the print.

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles
B. Peters, S Santner, C. Donsbach, P. Vöpel, Bernd Smarsly S. Dehnen,
Chem. Sci., 2019, 10, 5211–5217.
K2Hg2Te3 – Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material
G. Thiele, P. Bron, S. Lippert, F. Nietschke, O. Oeckler, M. Koch, B. Roling, S. Dehnen,
Inorg. Chem., 2019, 58, 7, 4052–4054 .

Synthesis and Structures of Compounds with Molecular, One-Dimensional or Two-Dimensional Selenido Cadmate Anions
I. Nußbruch, S. Dehnen,
Z. Anorg. Allg. Chem., 2018, 644, 1897–1901.

Formation of [(CnC1imTe)4Hg]2+ (n = 6, 8) upon In-Situ Generation of Dialkylimidazole-2-Tellurones in Ionic Liquids at Room Temperature
C. Donsbach, S. Dehnen,
Eur. J. Inorg. Chem., 2018, 40, 4429–4433.

F(C4C1Im)6[Hg7Se10]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids
C. Donsbach, S. Dehnen,
Z. Anorg. Allg. Chem., 2018, 644, 1383–1386.

Multi-Valent Group 14 Chalcogenide Architectures from Ionic Liquids: 0-{[Cs@SnII4(GeIV4Se10)4]7-} and 2D-{[SnII(GeIV4Se10)]2-}
S. Santner, A. Wolff, M. Ruck, S. Dehnen,
Chem. Eur. J., 2018, 24, 11899–11903 (Inside Back Cover).

[Hg4Te8(Te2)4]8–: A Heavy Metal Porphyrinoid Embedded in a Lamellar Structure
C. Donsbach, K. Reiter, D. Sundholm, F. Weigend, S. Dehnen,
Angew. Chem., 2018, 129, 8906–8910.
Angew. Chem. Int. Ed., 2018, 57, 8770–8774.

The Role of [BF4]- and [B(CN)4]- Anions in the Ionothermal Synthesis of Chalcogenidometalates
S. Santner, J. Sprenger, M. Finze, S. Dehnen,
Chem. Eur. J., 2018, 24, 3474–3480 (Inside Front Cover, Hot Paper).

Exploring the Chemical Reaction Space at the Formation of Chalcogenidometalate Superspheres in Ionic Liquids
S. Santner, S. Yogendra, J. J. Weigand, S. Dehnen,
Chem. Eur. J., 2017, 23, 1999–2004 (Frontispiece).

Crystalline Chalcogenido Metalates – Synthetic Approaches for Materials Synthesis and Transformation
G. Thiele, S. Santner, S. Dehnen,
Z. Kristallogr., 2017, 232, 47–54.

Synthese intermetallischer Übergangs-Hauptgruppenmetall-Nanopartikel in ionischen Flüssigkeiten

Heat capacities of ionic liquids based on tetrahydrothiophenium cation and NTf2 anion
D. H. Zaitsau, A. Schmitz, C. Janiak, S. P. Verevkin,
Thermochim. Acta, 2020, 686, 178547.
Synthesis of plasmonic Fe/Al nanoparticles in ionic liquids
A. Schmitz, H. Meyer, M. Meischein, A. Garzón Manjón, L. Schmolke, B. Giesen, C. Schlüsener, P. Simon, Y. Grin, R. A. Fischer, C. Scheu, A. Ludwig, C. Janiak,
RSC Adv., 2020, 10, 12891–12899.
Acylselenoureato bis(chelates) of lead: Synthesis, structural characterization and microwave-assisted formation of PbSe nano- and microstructures

K. Klauke, A. Schmitz, A.-C. Swertz, B. B. Beele, B. Giesen, C. Schlüsener, C. Janiak, F. Mohr,
New J. Chem., 2020, 44, 7719–7726.
Odd–even effect for efficient bioreactions of chiral alcohols and boosted stability of the enzyme
M. Bülow, A. Schmitz, T. Mahmoudi, D. Schmidt, F. Junglas, C. Janiak, C. Held,
RSC Adv. 2020, 10, 28351–28354.

Rhodium nanoparticles supported on covalent triazine-based frameworks as re-usable catalyst for benzene hydrogenation and hydrogen evolution reaction
M. Siebels, C. Schlüsener, J. Thomas, Y.-X. Xiao, X.-Y. Yang, C. Janiak,
J. Mater. Chem. A, 2019, 7, 11934–11943.

Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids
I. Simon, J. Hornung, J. Barthel, J. Thomas, M. Finze, R. A. Fischer, C. Janiak,
Beilstein J. Nanotechnol., 2019, 10, 1754–1767.
Bimetallic Co/Al nanoparticles in an ionic liquid: synthesis and application to alkyne hydrogenation

L. Schmolke, B. J. Gregori, B. Giesen, A. Schmitz, J. Barthel, L. Staiger, R. A. Fischer, A. Jacobi von Wangelin, C. Janiak,
New J. Chem., 2019, 43, 16583−16594.

Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Dalton Trans., 2019, 11, 4073.

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand
M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel, C. Janiak,
Dalton Trans., 2018, 47, 8892.

Synthesis of Rare Earth Metal and Rare Earth Metal Fluoride Nanoparticles in Ionic Liquids and Propylene Carbonate
M. Siebels, L. Mai, L. Schmolke, K. Schütte, J. Barthel, J. Yue, J. Thomas, B. Smarsly, A. Devi, R. A. Fischer, C. Janiak,
Beilstein J. Nanotechnol., 2018, 9, 1881–1894.

Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles
K. Klauke, D. H. Zaitsau, M. Bülow, L. He, M. Klopotowski, T.-O. Knedel, J. Barthel, C. Held, S. P. Verevkin, C. Janiak,
Dalton Trans., 2018, 47 (14), 5083–5097.

Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety
K. Klauke, I. Gruber, T.-O. Knedel, L. Schmolke, J. Barthel, H. Breitzke, G. Buntkowsky, C. Janiak,
Organometallics, 2018, 37 (3), 298–308.

Synthesis of metal-fluoride nanoparticles supported on thermally reduced graphite oxide
A. Schmitz, K. Schütte, V. Ilievski, J. Barthel, L. Burk, R. Mülhaupt, J. Yue, B. Smarsly, C. Janiak,
Beilstein J. Nanotechnol., 2017, 8, 2474–2483.

Multifunktionale weiche Materialien basierend auf Borat-haltigen Ionischen Flüssigkeiten und Lanthaniden

Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscosity Ionic Liquids
J. Landmann, J. A. P. Sprenger, P. T. Hennig, R. Bertermann, M. Grüne, F. Würthner, N. V. Ignat'ev, M. Finze,
Chem. Eur. J., 2018, 24, 608.

Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids
L. A. Bischoff, J. A. P. Sprenger, P. T. Hennig, N. V. Ignat'ev, M. Finze,
Z. Anorg. Allg. Chem., 2018, 644, 1285.

The Role of [BF4]– and [B(CN)4]– Anions in the Ionothermal Synthesis of Chalcogenidometalates
S. Santner, J. A. P. Sprenger, M. Finze, S. Dehnen,
Chem. Eur. J. , 2018, 24, 3474.

Lanthanide Coordination Polymers and MOFs Based on the Dicyanodihydridoborate Anion
S. H. Zottnick, G. D. Wiebke, C. Kerpen, M. Finze, K. Müller-Buschbaum,
Chem. Eur. J. , 2018, 24, 15287–15294.

Transformation of [EMIm][BPB] into a Cationic Luminescent Ln-Coordination Polymer with the Bis(phthalato)borate Anion
S. H., Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum,
Z. Anorg. Allg. Chem., 2018, 644, 1445–1450.

Löslichkeit von molekularen und ionischen Präkursoren in ionischen Flüssigkeiten

Ionic liquids alkyl-imidazolium thiocyanates: Comprehensive thermochemical study
D. H. Zaitsau, A. V. Yermalayeu, S. P. Verevkin
Journal of Molecular Liquids, 2021, 321, 114284.
Extremely low vapor-pressure data as access to PC-SAFT parameter estimation for ionic liquids and modeling of precursor solubility in ionic liquids
M. Bülow, M. Greive, D. H. Zaitsau, S. P. Verevkin, C. Held 
Chem. Open, 2021, 10, 216-226.
Prediction of salting-out in liquid-liquid two-phase systems with ePC-SAFT: Effect of the born term and of a concentration-dependent dielectric constant 
M. Ascani, C. Held  
ZAAC, 2021, 647, 1-11.
Predicting vapor–liquid equilibria for sour-gas absorption in aqueous mixtures of chemical and physical solvents or ionic liquids with ePC-SAFT 
M. Bülow, I. N. Gerek, S. Hirohama, G. Sadowski, C. Held  
Industrial & Engineering Chemistry Research, 2021, 60, 6327-6336.
Tetrahydrothiophene-based ionic liquids: Synthesis and thermodynamic characterizations
A. Schmitz, M. Bülow, D. Schmidt, D. H. Zaitsau, F. Junglas, T.-O. Knedel, S. P. Verevkin, Ch. Held, Ch. Janiak
Chem. Open, 2021, 10(2), 153-163.
From volatility to solubility: Thermodynamics of imidazolium-based ionic liquids containing chloride and bromide anions
D. H. Zaitsau, R Siewert, A. A. Pimerzin, M. Bülow, Ch. Held, M. Loor, St. Schulz, S. P. Verevkin
Journal of Molecular Liquids, 2021, 323, 114998.
Volatility of molten salts [Ph4P][NTf2] and Cs[NTf2]
D. H. Zaitsau, M. Gantman, P. Schulz, P. Wasserscheid, S. P. Verevkin
Chem. Open, 2021, 10(2), 199-204.
In the footsteps of August Michaelis: Syntheses and thermodynamics of extremely low-volatile ionic liquids
D. H. Zaitsau, A. Topp, A. Siegesmund, A. Päpke, M. Köckerling, S. P. Verevkin
Chem. Open, 2021, 10(2), 243-247.
Weaving a network of reliable thermochemistry around lignin building blocks: Methoxy-phenols and methoxy-benzaldehydes
S. Verevkin, M. Konnova, V. Turovtsev, A. Riabchunova, A. Pimerzin,
Industrial & Engineering Chemistry Research, 2020, 59(52).
Synthesis and properties of 1,2,3-triethoxypropane: A glycerol-derived green solvent candidate
S. Qian, X. Liu, V. Emel’yanenko, P. Sikorski, I. Kammakakam, B. Flowers, T. Jones, Ch. Turner, S. Verevkin, J. Bara
Ind. Eng. Chem. Res., 2020, 59(45), 20190-20200.
Vaporization thermodynamics of 1-ethyl-3-methylimidazolium diethyl phosphate
D. H. Zaitsau, S. P. Verevkin
Russian Journal of Inorganic Chemistry, 2020, 65, 699–702.
Heat capacities of ionic liquids based on tetrahydrothiophenium cation and NTf2 anion
D. H. Zaitsau, A. Schmitz, Ch. Janiak, S. P. Verevkina
Thermochimica Acta, 2020, 686, 178547.
Thermochemistry of di-substituted benzenes: nitro- and dimethylamino benzaldehydes
R. Siewert, A. A. Samatov, R. N. Nagrimanov, S. P. Verevkin
J. Chem. Thermodynamics, 2020, 143, 106060.
Thermochemistry of di-substituted benzenes: Ortho-, meta-, and para-hydroxyacetophenones
I. V. Andreeva, M. A. Varfolomeev, S. P. Verevkin
J. Chemical Thermodynamics, 2020, 140, 105893.
The relative thermodynamic stability of diamond and graphite
M. A. White, S. Kahwaji, V. L. S. Freitas, R. Siewert, J. Weatherby, M. D. M. C. Ribeiro da Silva, S. P. Verevkin, E. R. Johnsona, J. W. Zwanzigera
Angew. Chem. Int. Ed., 2020, 60(3), 1546-1549.
High-pressure-mediated thiourea-organocatalyzed asymmetric Michael addition to (hetero)aromatic nitroolefins: Prediction of reaction parameters by PCP-SAFT modelling
Th. Weinbender; M. Knierbein; L. Bittorf; Ch. Held; R. Siewert; S. P. Verevkin; G. Sadowski; O. Reiser
ChemPlusChem, 2020, 85(6), 1292-1296.
Thermochemistry of phthalic acids: Evaluation of thermochemical data with complementary experimental and computational methods
R. Siewert, V. N. Emel´yanenko, S. P. Verevkin
Fluid Phase Equilibria, 2020, 517, 112582.
Paving the way to solubility through volatility: Thermodynamics of imidazolium-based ionic liquids of the type [CnC1Im][I]
D. H. Zaitsau, R. Siewert, A. A. Pimerzin, M. Bülow, Ch. Held, M. Loore, St. Schulze, S. P. Verevkin
Fluid Phase Equilibria, 2020, 522, 112767.
Thermochemistry of the lignin broken bits
S. P. Verevkin, V. N. Emel´yanenko, R. Siewert, A. A. Pimerzin
Fluid Phase Equilibria, 2020, 522, 112751.
Symmetry vs. asymmetry – enthalpic differences in imidazolium-based ionic liquids
A. V. Yermalayeu, M. A. Varfolomeev, S. P. Verevkin
Journal of Molecular Liquids, 2020, 317, 114150.

Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids
L. Schmolke, S. Lerch, M. Bühlow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, Th. Strassner, C. Janiak,
Nanoscale, 2019, 11, 4073-4082.
Encyclopedia of ionic liquids: Liquid-liquid equilibria of binary and ternary systems containing ionic liquids
M. Bülow, A. Danzer, Ch. Held
https://doi.org/10.1007/978-981-10-6739-6 
Vapour pressures and enthalpies of vaporisation of alkyl formamides
K. V. Zaitseva, D. H. Zaitsau, M. A. Varfolomeev, S. P. Verevkin
Fluid Phase Equilibria, 2019, 494, 228-238.
Imidazolium-based ionic liquids containing FAP anion: Thermodynamic study
D. H. Zaitsau, S. P. Verevkin
Journal of Molecular Liquids, 2019, 287, 110959.
Thermodynamic properties of systems comprising esters: Experimental data and modeling with PC-SAFT and SAFT-y mie
N. Haarmann, R. Siewert, A. A. Samarov, S. P. Verevkin, G. Sadowski, Ch. Held
Ind. Eng. Chem. Res., 2019, 58(16), 6841–6849.
Incorporating a concentration-dependent dielectric constant into ePC-SAFT. An application to binary mixtures containing ionic liquids 
M. Bülow, X. Ji, Ch. Held
Fluid Phase Equilibria, 2019, 492, 26-33.

Vaporization thermodynamics of ionic liquids with tetraalkylphosphonium cations
D. H. Zaitsau, N. Plechkova, S. P. Verevkin,
J. Chem. Thermodyn., 2019, 130, 204–212.
Thermochemistry of drugs: Experimental and theoretical study of analgesics
R. N. Nagrimanov, M. A. Ziganshin, B. N. Solomonov, S. P. Verevkin,
Struct. Chem., 2019, 30, 247–261.
Energetic structure-property relationships in thermochemistry of halogenosubstituted benzoic acids
K. V. Zherikova, S. P. Verevkin,
Journal of Thermal Analysis and Calorimetry, 2019, 138, 4045–4059.

Arnold-Eucken-Preis 2018 für Christoph Held
Tunable hydrophobic eutectic solvents based on terpenes and monocarboxylic acids
M. A. R. Martins, E. A. Crespo, P. V. A. Pontes, L. P. Silva, M. Bülow, G. J. Maximo, E. A. C. Batista, Ch. Held, S. P. Pinho, J. A. P. Coutinho
ACS Sustainable Chem. Eng., 2018, 6(7), 8836-8846.
The role of polyfunctionality in the formation of [Ch]Cl-carboxylic acid-based deep eutectic solvents
E. A. Crespo, L. P. Silva, M. A. R. Martins, M. Bülow, O. Ferreira, G. Sadowski, Ch. Held, S. P. Pinho, J. A. P. Coutinho
Ind. Eng. Chem. Res., 2018, 57(32), 11195-11209.

Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles
K. Klauke, D. H. Zaitsau, M. Bülow, L. He, M. Klopotowski, T.-O. Knedel, J. Barthel, C. Held, S. P. Verevkin, C. Janiak,
Dalton Trans., 2018, 47 (14), 5083–5097.

Hydrogen bonding of molecular solutes in protic and aprotic ionic liquids
A. A. Khachatrian, Z. I. Shamsutdinova, I. T. Rakipov, M. A. Varfolomeev, B. N. Solomonov, S. P. Verevkin,
Journal of Molecular Liquids, 2018, 271, 815–819.

Thermodynamics and proton activities of protic ionic liquids with quantum cluster equilibrium theory
J. Ingenmey, M. von Domaros, E. Perlt, S. P. Verevkin, B. Kirchner,
Journal of Chemical Physics, 2018, 148, 193822.

Imidazolium based ionic liquids containing methanesulfonate anion: Comprehensive thermodynamic study
D. H. Zaitsau, A. V. Yermalayeu, A. A. Pimerzin, S. P. Verevkin,
Chemical Engineering Research and Design, 2018, 137, 164–173.

Substituted benzamides and substituted benzoic acids: Like tree, like fruit?
S. P. Verevkin, V. N. Emel'yanenko, D. H. Zaitsau,
ChemPhysChem., 2018, 19, 619–630.

Imidazolium based ionic liquids containing trifluoroacetate anion: Comprehensive thermodynamic study
D. H. Zaitsau, S. P. Verevkin,
Journal of Solution Chemistry, 2018, 47 (5), 892–905.

Solubility predictions of acetanilide derivatives in water: Combining thermochemistry and thermodynamic modeling
Ch. Held, J. Brinkmann, A.-D. Schröder, M. I. Yagofarov, S. P. Verevkin,
Fluid Phase Equilibria, 2018, 455, 43–53.

Thermodynamics of imidazolium-based ionic liquids containing the trifluoromethanesulfonate anion
D. H. Zaitsau, A. V. Yermalayeu, V. N. Emel’yanenko, S. P. Verevkin,
Chemical Engineering & Technology, 2018, 41, 1604–1612.

Melting temperature and heat of fusion of cytosine revealed from fast scanning calorimetry
A. Abdelaziz, D. H, Zaitsau, T. A. Mukhametzyanov, B. N. Solomonov, P. Cebe, S. P. Verevkin, C. Schick,
Thermochimica Acta, 2017, 657, 47–55.

Carbonate based ionic liquid synthesis (CBILS®): Development of continuous flow method for preparation of ultra-pure ionic liquids
R. S. Kalb, M. Damm, S. P. Verevkin,
React. Chem. Eng., 2017, 2, 432–436.

Thermochemical properties of tunable aryl alkyl ionic liquids (TAAILs) based on phenyl-1H-imidazoles
D. H. Zaitsau, M. Kaliner, S. Lerch, Th. Strassner, V. N. Emel’yanenko, S. P. Verevkin,
Z. Anorg. Allg. Chem., 2017, 643, 114–119.

Synthese anorganischer Materialien in ionischen Flüssigkeiten: Aufklärung der Reaktionsmechanismen vom Komplex zum Kristall

Strong Microheterogeneity in Novel Deep Eutectic Solvents
V. Alizadeh, D. Geller, F. Malberg, P. B. Sánchez, A. Padua, B Kirchner,
ChemPhysChem, 2019, 20 (14), 1786–1792.

Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type
M. M. Azim, A. Pensado, B. Kirchner, T. Gutmann, P. B. Groszewicz, G. Buntkowsky, A. Stark,
Microporous and Mesoporous Mater., 2018, 266, 204–213.

Molecular Dynamics Simulations of Lithium Doped Ionic-Liquid Electrolytes
P. Ray, A. Balducci, B. Kirchner,
J. Phys. Chem. B, 2018, 122, 10535–10547.

Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO2 in Ionic Liquids
P. Voepel, C. Seitz, J. M. Waack, S. Zahn, T. Leichtweiß, A. Zaichenko, D. Mollenhauer, H. Amenitsch, M. Voggenreiter, S. Polarz, B. M. Smarsly,
Cryst. Growth Des., 2017, 17 (10), 5586–5601.

Photocatalytic activity of multiphase TiO2(B)/anatase nanoparticle heterojunctions prepared from ionic liquids
P. Voepel, M. Weiss, B. M. Smarsly, R. Marschall,
Journal of Photochemistry and Photobiology A: Chemistry, 2018, 366, 34–40.

Hydrophilic Ionic Liquid Mixtures of Weakly and Strongly Coordinating Anions with and without Water
R. Macchieraldo, L. Esser, R. Elfgen, P. Voepel, S. Zahn, B. M. Smarsly, B. Kirchner,
ACS Omega, 2018, 3, 8567–8582.

How to harvest Grotthuss diffusion in protic ionic liquid electrolyte systems
B. Kirchner, J. Ingenmey, S. Gehrke,
ChemSusChem, 2018, 11, 1900–1910.

Thermodynamics and proton activities of protic ionic liquids with quantum cluster equilibrium theory
J. Ingenmey, M. von Domaros, E. Perlt, S. P. Verevkin, B. Kirchner,
J. Chem. Phys., 2018, 148, 193822.

Spontaneous Substitutins on Phosphorus Trihalides in Imidazolium Halide Ionic Liquids: A Grotthus Diffusion of Anions?
O. Hollóczki, A. Wolff, J. Pallmann, R. Whiteside, J. Hartley, M. A. Grasser, P. Nockemann, E. Brunner, T. Doert, M. Ruck,
Chem. Eur. J., 2018, 24, 16323-16331.

Structure and lifetimes in ionic liquids and their mixtures
S. Gehrke, M. von Domaros, R. Clark, O. Hollóczki, M. Brehm, T. Welton, A. Luzar, B. Kirchner,
Faraday Discuss., 2018, 206, 219–245.

A Molecular Level Understanding of Template Effects in Ionic Liquids
R. Elfgen, O. Hollóczki, B. Kirchner,
Acc. Chem. Res., 2017, 50, 2949–2957.

Theoretical Investigation of the Te4Br2 Molecule in Ionic Liquids
R. Elfgen, O. Hollóczki, P. Ray,, M. F. Groh, M. Ruck, B. Kirchner,
Z. Anorg. Allg. Chem., 2017, 643(1), 51-52.

Predicting the Ionic Product of Water
E. Perlt, M. von Domaros, B. Kirchner, R. Ludwig, F. Weinhold,
Sci. Rep., 2017, 7(1), 1-10.

Neue frühe Übergangsmetallatom-Clustermaterialien: In und mit Ionischen Flüssigkeiten

Cation-anion pairs of niobium clusters of the type [Nb6Cl12(RCN)6][Nb6Cl18] (R = Et, nPr, iPr) with nitrile ligands RCN forming stabilizing inter-ionic contacts
Dedicated to Prof. Arndt Simon on the Occasion of his 80th Birthday
E. Sperlich, M. Köckerling,
Z. Naturforsch., 2020, 75b, 173-181.

Low-Melting Manganese(II)-Based Ionic Liquids: Syntheses, Structures, Properties and Influence of Trace Impurities
T. Peppel, M. Geppert-Rybczynska, C. Neise, U. Kragl, M. Köckerling,
Materials, 2019, 12, 3764.

Poly[1-ethyl-3-methylimidazolium [tri-l-isothiocyanato- manganate(II)]]
T. Peppel, M. Köckerling,
IUCrData, 2019, 4, x191659.

[Nb6Cl12(HIm)6](OAc)2·3MeOH – a hydrogen bonded network of niobium cluster cations, acetate anions and methanol molecules
E. Sperlich, M. Köckerling,
Z. Naturforsch., 2019, 74b, 751–755.

A Hexanuclear Niobium Cluster Compound Crystallizing as Macroscopic Tubes
J. König, M. Köckerling,
Chem. Eur. J., 2019, 25, 13905–13910.
Image selected for cover page

Discrete Neutral Niobium Cluster Units in Compounds of the Type [Nb6Cl14L4] with L = O or N Donor Ligand
Dedicated to Prof. Thomas Fässler on the Occation of his 60th Birthday
E. Sperlich, J. König, D. H. Weiß, F. Schröder, M. Köckerling,
Z. Anorg. Allg. Chem., 2019, 645, 233–241.

Bis(tetramethylguanidinium) hexachloridotellurate(IV)
N. O. Giltzau, M. Köckerling,
IUCrData, 2018, 3, x181488.

(C7H6NS)2[Nb6Cl18]·2C4H8O: First niobium cluster with an N,S-heterocyclic cation
E. Sperlich, M. Köckerling,
IUCrData, 2018, 3, x181760.

A Hexanuclear Niobium Cluster Compound With Intra-Cluster Chelate Ligands: [Nb6(OC2H4NH2)12]I3
D. H. Weiß, M. Köckerling,
Chem. Eur. J., 2018, 24, 18613–18617.
Image selected for frontispiece

An Uncommon Complex Cation Stabilized by a Niobium Cluster Anion: [Al(CH3CN)5Br][Nb6Cl12iBr6a]·3CH3CN
I. Dartsch, J. König, M. Köckerling,
J. Clus. Sci., 2018, 29, 319–323.

Low Melting Tetracyanidoborate Salts with Alkyl-, Arylammonium, and Pyridinium Cations: Syntheses, Structures, Properties
A. Siegesmund, A. Topp, C. Nitschke, M. Köckerling,
ChemistrySelect, 2017, 2, 11328–11335.

Syntheses and Structures of New Rare-Earth Metal Tetracyanidoborates
F. Falk, L. Herkert, L. Hackbarth, K. Müller-Buschbaum, M. Köckerling,
Z. Anorg. Allg. Chem., 2017, 643, 625–630.

ILPIN: Ionische Flüssigkeiten als Vorläufer für anorganische Nanomaterialien

The crystal structure of N-butylpyridinium bis(µ2-dichlorido)-tetrachloridodicopper(II), C18H28N2Cu2Cl6
A. Abouserie, U. Schilde, A. Taubert,
Z. Kristallogr. NCS, 2018, 233 (4), 743–746.

The ionic liquid [Bmim][FeCl4] catalyzes the formation of iron doped mesoporous silica aerogels for H2O2 decomposition
A. Taubert, R. Löbbicke, K. Behrens, D. Steinbrück, L. Kind, T. Zhao, Ch. Janiak,
Matters, 2018.
DOI: 10.19185/matters.201803000004

CuS nanoplates from ionic liquid precursors—Application in organic photovoltaic cells
Y. Kim, B. Heyne, A. Abouserie, Ch. Pries, Ch. Ippen, Ch. Günter, A. Taubert, A. Wedel,
J. Chem. Phys., 2018, 148, 193818.

Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior
A. Abouserie K. Zehbe Ph. Metzner A. Kelling Ch. Günter U. Schilde, P. Strauch, Th. Körzdörfer, A. Taubert,
Eur. J. Inorg. Chem., 2017, 5640–5649.

Materialien aus reduzierbaren Oxiden: Wissensbasierte Entwicklung neuer Tieftemperatur-Synthesemethoden

Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
T. Xu, T. Waehler, J. Vecchietti, A. Bonivardi, T. Bauer, J. Schwegler, P.S. Schulz, P. Wasserscheid, J. Libuda
Angew. Chem. Int. Ed., 2017, 56, 9072.
Interaction of Ester-Functionalized Ionic Liquids with Atomically-Defined Cobalt Oxides Surfaces: Adsorption, Reaction and Thermal Stability
T. Xu, T. Waehler, J. Vecchietti, A. Bonivardi, T. Bauer, J. Schwegler, P.S. Schulz, P. Wasserscheid, Peter, J. Libuda
ChemPhysChem, 2017, 18, 3443.
ZnO Nanoparticle Formation from the Molecular Precursor [MeZnOtBu] by Ozone Treatment in Ionic Liquids: in-situ Vibrational Spectroscopy in an Ultrahigh Vacuum Environment 
T. Bauer, M. Voggenreiter, T. Xu, T. Wähler, F. Agel, K. Pohako-Esko, P. Schulz, T. Dopper, A. Görling, S. Polarz, P. Wasserscheid, J. Libuda
Z. Anorg. Allg. Chem., 2017, 643, 31-40.
Low-Temperature Synthesis of Oxides in Ionic Liquids: Ozone-Mediated Formation of Co3O4 Nanoparticles Monitored by In Situ Infrared Spectroscopy
T. Bauer, F. Agel, D. Blaumeiser, S. Maisel, A. Görling, P. Wasserscheid, J. Libuda
Adv. Mater. Interfaces, 2019, 6, 1900890.
Dynamic CO Adsorption and Desorption through the Ionic Liquid Layer of a Pt Model Solid Catalyst with Ionic Liquid Layers
C. Schuschke, C. Hohner, C. Stumm, M. Kettner, L. Fromm, A. Goerling, J. Libuda
J. Phys. Chem. C, 2019, 123, 31057.
Model Studies on the Ozone-Mediated Synthesis of Cobalt Oxide Nanoparticles from Dicobalt Octacarbonyl in Ionic Liquids
R. Schuster, T. Wähler, M. Kettner, F. Agel, T. Bauer, P. Wasserscheid, J. Libuda
Chem. Open, 2020, https://doi.org/10.1002/open.202000187.

Niedertemperatur-Synthesen von thermoelektrischen Materialien durch thermische Zersetzung von maßgeschneiderten metallorganischen Prekursoren in ionischen Flüssigkeiten

Ionic Liquid-Based Low-Temperature Synthesis of Phase-Pure Tetradymite-Type Materials and Their Thermoelectric Properties
M. Loor, S. Salloum, P. Kawulok, S. Izadi, G. Bendt, J. Guschlbauer, J. Sundermeyer, N. Pérez, K. Nielsch, G. Schierning, S. Schulz,
Inorg. Chem., 2020, 59, 6, 3428–3436.

Thermochemische Untersuchungen zu Phasenbildungsprozessen von Elementen und Verbindungen der Gruppe 15 und 16 bei Synthesen in ionischen Flüssigkeiten - Mechanismen der Auflösung, Strukturbildung und Abscheidung

Low-Temperature Ordering in the Cluster Compound (Bi8)Tl[AlCl4]3
M. Knies, M. Kaiser, M. Lê Anh, A. Efimova, Th. Doert, M. Ruck,
Inorganics, 2019, 7 (4), 45.

Pseudohalogenchemie in ionischen Flüssigkeiten it reaktiven Kationen und Anionen

Salts of HCN-Cyanide Aggregates: [CN(HCN)2]- and [CN(HCN)3]-

K. Bläsing, J. Harloff, A. Schulz, A. Stoffers, P. Stoer, A. Villinger,
Angew. Chem. Int. Ed., 2020, 59, 10508–10513.
Angew. Chem., 2020, 132, 10594–10599.
Hexacyanidosilicates with Functionalized Imidazolium Counterions

J. Harloff, K. C. Laatz, S. Lerch, A. Schulz, P. Stoer, T. Strassner, A. Villinger,
Eur. J. Inorg. Chem., 2020, 2457-2464.

Pseudo Halide Chemistry in Ionic Liquids with Decomposable Anions
J. Harloff, A. Schulz, P. Stoer, A. Villinger,
Z. Anorg. Allg. Chem., 2019, 645, 835–839.

Heavy Neutral and Anionic Pnictogen Thiocyanates
S. Arlt, J. Harloff, A. Schulz, A. Stoffers, A. Villinger,
Inorg. Chem., 2019, 58, 5305–5313.

Cyanidosilicates – Synthesis and Structure
J. Harloff, D. Michalik, S. Nier, A. Schulz, P. Stoer, A. Villinger,
Angew. Chem. Int. Ed. , 2019, 58, 5452–5456.
Angew. Chem., 2019, 131, 5506–5511.

Chalkogenid-basierte Ionische Flüssigkeiten in der Synthese von Metallchalkogenid- und Interchalcogenid-Materialien nahe Raumtemperatur

Homoleptic Trimethylsilylchalcogenolato Zincates [Zn(ESiMe3)3]– and Stannanides [Sn(ESiMe3)3] – (E = S, Se): Precursors in Solution-Based Low-Temperature Binary Metal Chalcogenide and Cu2ZnSnS4 (CZTS) Synthesis
J. Guschlbauer, T. Vollgraff, J. Sundermeyer,
Dalton Trans., 2020, 49, 2517–2526.

Ionic Liquid-Based Low-Temperature Synthesis of Phase-Pure Tetradymite-Type Materials and Their Thermoelectric Properties
M. Loor, S. Salloum, P. Kawulok, S. Izadi, G. Bendt, J. Guschlbauer, J. Sundermeyer, N. Pérez, K. Nielsch, G. Schierning, S. Schulz,
Inorg. Chem., 2020, 59, 6, 3428–3436.

Homoleptic Group 13 Trimethylsilylchalcogenolato Metalates [M(ESiMe3)4]- (M = Ga, In; E = S, Se): Metastable Precursors for Low-Temperature Syntheses of Chalcogenide-Based Materials
J. Guschlbauer, T. Vollgraff, J. Sundermeyer,
Inorg, Chem. , 2019, 58 (22), 15385–15392.

Systematic study on anion–cation interactions via doubly ionic H-bonds in 1,3-dimethylimidazolium salts comprising chalcogenolate anions MMIm [ER] (E = S, Se; R = H, tBu, SiMe3)
J. Guschlbauer, T. Vollgraff, J. Sundermeyer,
Dalton Trans, 2019, 48, 10971–10978.

Publikationen der ersten Förderperiode (2014 – 2017)

Intermetallische Cluster und Nanopartikel

Ionic Liquids as Size- and Shape-Regulating Solvents for the Synthesis of Cobalt Nanoparticles
S. Essig, S. Behrens,
Chem. Ing. Tech. 2015, 87, 1741–1747.

[(Pb6I8){Mn(CO)5}6]2– – an Octahedral (M6Xn)-like Cluster with Unprecedented Inverted Bonding
S. Wolf, K. Reiter, F. Weigend, W. Klopper, C. Feldmann,
Inorg. Chem. 2015, 54, 3989–3994.

Elektrochemische Synthese von Gallium- und Indium-Nanostrukturen und deren Oxide und Nitride mit Hilfe von Ionischen Flüssigkeiten und physikalischen Oberflächenmodifizierungsprozessen

Electroless Deposition of III-V Semiconductor Nanostructures from Ionic Liquids at Room Temperature
A. Lahiri, N. Borisenko, M. Olschewski, R. Gustus, J. Zahlbach, F. Endres,
Angew. Chem. Int. Ed. 2015, 54, 11870–11874.

Electrodeposition of GaN in the Presence of NH4Cl in an Ionic Liquid: Hints for GaN Formation
A. Lahiri, N. Borisenko, A. Borodin, F. Endres,
Chem. Commun. 2014, 50, 10438–10440.

Umsetzung komplexer, fester Vorläuferverbindungen bei niedrigen Temperaturen in maßgeschneiderten Ionischen Flüssigkeiten:
Neue Verbindungen und Einsichten in die Reaktionsprinzipien

Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles
V. N. Emel'yanenko, M. Kaliner, Th. Strassner, S. P. Verevkin
Fluid Phase Equilib. 2017, 433, 40–49.

Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles
D. H. Zaitsau, M. Kaliner, S. Lerch, Th. Strassner, V. N. Emel'yanenko, S. P. Verevkin
Z. Anorg. Allg. Chem. 2017, 643, 114–119.

An Amorphous Phase of Zinc and Silicon at Composition Zn2Si5 (:H, OH)
X.-J. Feng, B. Böhme, M. Bobnar, P. Simon, W. Carrillo-Cabrera, U. Burkhardt, M. Schmidt, U. Schwarz, M. Baitinger, T. Straßner, Yu. Grin,
Z. Anorg. Allg. Chemie 2017, 643, 106–113.

Redox Route from Inorganic Precursor Li2C2 to Nanopatterned Carbon
P. Simon, X.-J. Feng, M. Bobnar, P. Höhn, U. Schwarz, W. Carrillo-Cabrera, M. Baitinger, Yu. Grin,
ACS Nano, 2017, 11, 2, 1455–1465.

Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids
M. F. Groh, A. Wolff, M. A. Grasser, M. Ruck,
Int. J. Mol. Sci., 2016, 17 (9), 1452.

Controlled Synthesis of Pnicogen–Chalcogen Polycations in Ionic Liquids
M. F. Groh, A. Isaeva, U. Müller, P. Gebauer, M. Knies, M. Ruck,
Eur. J. Inorg. Chem., 2016, 6, 880–889.

Resource-Efficient High-Yield Ionothermal Synthesis of Microcrystalline Cu3–xP
A. Wolff, J. Pallmann, R. Boucher, A. Weiz, E. Brunner, Th. Doert, M. Ruck,
Inorg. Chem., 2016, 55, 8844–8851.
DOI: 10.1021/acs.inorgchem.6b01397

Polyhedral Bismuth Polycations Coordinating Gold(I) with Varied Hapticity in a Homoleptic Heavy-Metal Cluster
U. Müller, A. Isaeva, J. Richter, M. Knies, M. Ruck,
Eur. J. Inorg. Chem., 2016, 3580–3584.

Unexpected Reactivity of Red Phosphorus in Ionic Liquids
M. F. Groh, S. Paasch, A. Weiz, M. Ruck, E. Brunner,
Eur. J. Inorg. Chem., 2015, 3991–3994.
(selected for cover picture)

[P3Se4]+ – a Binary Phosphorus Selenium Cation
K.-O. Feldmann, J. Breternitz, M. F. Groh, U. Müller, M. Ruck, T. Wiegand, J. Ren,
H. Eckert, O. Schön, K. Karaghiosoff, B. Maryasin, C. Ochsenfeld, J. J. Weigand,
Chem. Eur. J., 2015, 21, 9697–9712.

Ionothermal Synthesis, Structure, and Bonding of the Catena-Heteropolycation (∞1)[Sb2 Se2]+
M. F. Groh, J. Breternitz, E. Ahmed, A. Isaeva, A. Efimova, P. Schmidt, M. Ruck,
Z. Anorg. Allg. Chem., 2015, 641, 388–393.

Bi2S3 Bipyramids in Layered Sulfides M2Bi2S3(AlCl4)2 (M = Ag, Cu)
M. F. Groh, M. Knies, A. Isaeva, M. Ruck,
Z. Anorg. Allg. Chem., 2015, 641, 279–284.

[Sb7Se8Br2]3+ and [Sb13Se16Br2]5+ – Double and Quadruple Spiro Cubanes from Ionic Liquids
E. Ahmed, J. Breternitz, M. Groh, A. Isaeva, M. Ruck,
Eur. J. Inorg. Chem., 2014, 19, 3037–3042.

Substitution of Conventional High–Temperature Syntheses of Inorganic Compounds by Near–Room
–Temperature Syntheses in Ionic Liquids
M. F. Groh, U. Müller, E. Ahmed, A. Rothenberger, M. Ruck
Z. Naturforsch., 2013, 68b, 1108.

Niedertemperatur-Zugang zu Solvensfreien Chalkogenidometall- Materialien

Syntheses and Properties of Selenido Mercurates with [HgSe2]2- Anions in Diverse Chemical Environments
C. Donsbach, S. Dehnen,
Inorg. Chem. Front., 2017, 4, 336–342.

Formation of Crystalline Telluridomercurates from Ionic Liquids near Room Temperature
C. Donsbach, S. Dehnen,
Z. Anorg. Allg. Chem., 2017, 643, 14–19.

Mercurates from a Revised Ionothermal Synthesis Route: The Pseudo-Flux Approach
C. Donsbach, G. Thiele, L. H. Finger, J. Sundermeyer, S. Dehnen,
Inorg. Chem., 2016, 55, 6725–6730.

Combining Solid State and Solution Based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates (II or IV)
G. Thiele, C. Donsbach, I. Nußbruch, S. Dehnen,
J. Vis. Exp., 2016, 118, e54789,
URL: https://www.jove.com/video/54789.

Crystalline Chalcogenides from Ionic Liquids
S. Santner, J. Heine, S. Dehnen,
Angew. Chem., 2016, 127, 876–983;
Angew. Chem., Int. Ed. 2016, 54, 886–904.

K2Hg2Se3: Large-Scale Synthesis of a Photoconductor Material Prototype with a Columnar Polyanionic Substructure
G. Thiele, S. Lippert, F. Fahrnbauer, P. Bron, O. Oeckler, A. Rahimi-Iman, M. Koch, B. Roling, S. Dehnen,
Chem. Mater., 2015, 27, 4114–4118.

[M4Sn4Se17]10- Cluster Anions (M = Mn, Zn, Cd) in Cs+ Environment and as Ternary Precursors for Ionothermal Treatment
precursors in ionic liquid or propylene carbonate with relevance to methanol synthesis
S. Santner, S. Dehnen,
Inorg. Chem., 2015, 54, 1188–1190.

Synthese intermetallischer Nanopartikel in ionischen Flüssigkeiten

Metal Nanoparticles in Ionic Liquids
S. Wegner, C. Janiak,
Top Curr Chem (Z), 2017, 375 (65).

Soft, Wet-Chemical Synthesis of Metastable Superparamagnetic Hexagonal Close-Packed Nickel Nanoparticles in Different Ionic Liquids
S. Wegner, Ch. Rutz, K. Schütte, J. Barthel, A. Bushmelev, A. Schmidt, K. Dilchert, R. Fischer, C. Janiak,
Chem. Eur. J., 2017, 23, 6330–6340.

Synthesis of metal nanoparticles and metal fluoride nanoparticles from metal amidinate precursors in 1-butyl-3-methylimidazolium ionic liquids and propylene carbonate
K. Schütte, J. Barthel, M. Endres, M. Siebels, B. Smarsly, J. Yue, C. Janiak,
Chem. Open, 2017, 6 (1), 137–148.

Anion analysis of ionic liquids and ionic liquid purity assessment by ion chromatography
C. Rutz, L. Schmolke, V. Gvilava, C. Janiak,
Z. Anorg. Allg. Chem., 2017, 643 (1), 130–135.

Synthesis and application of metal nanoparticle catalysts in ionic liquid media using metal carbonyl complexes as precursors
R. Marcos Esteban, C. Janiak,
Nanocatalysis in Ionic Liquids (M. Prechtl, Ed.) copyright 2017 Wiley-VCH, Weinheim, chapter 8, 147-169.
Published Online: 7 OCT 2016, Print ISBN: 9783527339105, Online ISBN: 9783527693283

Soft wet-chemical synthesis of Ru-Sn nanoparticles from single-source ruthenocene-stannole precursors in an ionic liquid
S. Wegner, M. Saito, J. Barthel, C. Janiak,
J. Organomet. Chem., 2016, 821, 192–196.

Comparative Synthesis of Cu and Cu2O Nanoparticles from Different Copper Precursors in an Ionic Liquid or Propylene Carbonate
R. M. Esteban, H. Meyer, J. Kim, J. Barthel, C. Gemel, R. A. Fischer, C. Janiak,
Eur. J. Inorg. Chem., 2016, 13-14, 2106–2113.

Use of a 4,5-Dicyanoimidazolate Anion Based Ionic Liquid for the Synthesis of Iron and Silver Nanoparticles
S. S. Mondal, D. Marquardt, C. Janiak, H.-J. Holdt,
Dalton Trans., 2016, 45, 5476–5483.

Synthesis of ruthenium@graphene nanomaterials in propylene carbonate as re-usable catalysts for the solvent-free hydrogenation of benzene
R. M. Esteban, K. Schütte, D. Marquardt, J. Barthel, F. Beckert, R. Mülhaupt, C. Janiak,
Nano-Struct. Nano-Obj., 2015, 2, 28–34.

Iridium@graphene composite nanomaterials synthesized in ionic liquid as re-usable catalysts for solvent-free hydrogenation of benzene and cyclohexene
R. M. Esteban, K. Schütte, P. Brandt, D. Marquardt, H. Meyer, F. Beckert, R. Mülhaupt, H. Kölling, C. Janiak,
Nano-Struct. Nano-Obj., 2015, 2, 11–18.

Bis((dialkylamino)alkylselenolato)metal complexes as precursors for microwave-assisted synthesis of semiconductor metal selenide nanoparticles of zinc and cadmium in the ionic liquid [BMIm][ BF4]
K. Klauke, B. Hahn, K. Schütte, J. Barthel, C. Janiak,
Nano-Struct. Nano-Obj., 2015, 1, 24–31.

Synthesis of Cu, Zn and bimetallic Cu/Zn brass alloy nanoparticles from metal amidinate precursors in ionic liquid or propylene carbonate with relevance to methanol synthesis
K. Schütte, H. Meyer, C. Gemel, J. Barthel, R. A. Fischer, C. Janiak,
Nanoscale, 2014, 6, 5532–5544.

Colloidal nickel/gallium nanoalloys obtained from organometallic precursors in conventional organic solvents and in ionic liquids: Noble-metal-free alkyne semihydrogenation catalysts
K. Schütte, A. Doddi, C. Kroll, H. Meyer, C. Wiktor, C. Gemel, G. van Tendeloo, R. A. Fischer, C. Janiak,
Nanoscale, 2014, 6, 3116–3126.

Multifunktionale weiche Materialien basierend auf Borat-haltigen Ionischen Flüssigkeiten und Lanthaniden

Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion
S. H. Zottnick, M. T. Seuffert, Ch. Kerpen, M. Finze, Klaus Müller-Buschbaum,
Eur. J. Inorg. Chem., 2017, 2017, 4668.

Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion
T. Ribbeck, S. H. Zottnick, C. Kerpen, J. Landmann, N. V. Ignat'ev, K. Müller-Buschbaum, M. Finze,
Inorg. Chem., 2017, 56 (4), 2278–2286.

Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions
S. H. Zottnick, M. Finze, K. Müller-Buschbaum,
Chem. Commun., 2017, 53, 5193–5195.

Cover Picture: Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions
C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. Ignat'ev, M. Finze,
Angew. Chem. Int. Ed., 2017, 56, 2515.

Deprotonation of a Hydridoborate Anion
J. Landmann, F. Keppner, D. B. Hofmann, J. A. P. Sprenger, M. Häring, S. H. Zottnick, K. Müller-Buschbaum, N. V. Ignat'ev, M. Finze,
Angew. Chem. Int. Ed., 2017, 56, 2795–2799.

Bis(salicylato)borate as Versatile Sensitizer for Highly Luminescent Lanthanide Oxoborates from the Ultraviolet to Near Infrared with 4f and 5d Participation of the Lanthanides
S. H. Zottnick, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum,
Eur. J. Inorg. Chem., 2017, 10, 1355–1363.

Syntheses and Structures of New Rare-Earth Metal Tetracyanidoborates
F. Falk, L. Herkert, L. Hackbarth, K. Müller-Buschbaum, M. Finze, M. Köckerling,
Z. Anorg. Allg. Chem., 2017, 643, 625–630.

Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates
S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum,
Z. Anorg. Allg. Chem., 2017, 643, 53–59.

Protonation Versus Oxonium Salt Formation – Basicity and Stability Tuning of Cyanoborate Anions
C. Kerpen, J. A. P. Sprenger, L. Herkert, M. Schäfer, L. A. Bischoff, P. Zeides, M. Grüne, R. Bertermann, F. A. Brede, K. Müller-Buschbaum, N. V. Ignat’ev, M. Finze,
Angew. Chem., 2017, 56 (10), 2800–2804 .

Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion
T. Ribbeck, S. H. Zottnick, C. Kerpen, J. Landmann, N. V. Ignat’ev, K. Müller-Buschbaum, M. Finze,
Inorg. Chem., 2017, 56 (4), 2278–2286.

Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates
S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum,
Z. Anorg. Allg. Chem., 2017, 643, 53–59.

Synthesis and Properties of Organic Hexahalocerate(III) Salts
K. Pohako-Esko, T. Wehner, T. Bauer, P. S. Schulz, F. W. Heinemann, K. Müller-Buschbaum, P. Wasserscheid,
Eur. J. Inorg. Chem., 2016, 1333–1339.

The Hexacyanodiborane(6) Dianion [B2(CN)6]2-
J. Landmann, J. A. P. Sprenger, M. Hailmann, V. Bernhardt-Pitchougina, H. Willner, N. Ignat'ev, E. Bernhardt, M. Finze,
Angew. Chem., 2015, 127, 11411–11416;
Angew. Chem., Int. Ed. Engl., 2015, 54, 11259–11264.

18[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions
S. H. Zottnick, J. R. Sorg, J. A. P. Sprenger, M. Finze, K. Müller-Buschbaum,
Z. Anorg. Allg. Chem., 2015, 641, 164–167.

Synthese neuartiger MOF-Materialien aus strukturgebenden und funktionalisierten ionischen Flüssigkeiten

Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor
M. Fischer, J. Schwegler, C. Paula, P. S. Schulz and M. Hartmann,
Dalton Trans., 2016, 45, 18443–18446.

Ionic-Liquid-Modified Hybrid Materials Prepared by Physical Vapor Codeposition: Cobalt and Cobalt Oxide Nanoparticles in [C1C2Im][OTf] Monitored by In Situ IR Spectroscopy
S. Mehl, T. Bauer, O. Brummel, K. Pohako-Esko, P. Schulz, P. Wasserscheid, J. Libuda,
Langmuir, 2016, 32 (34), 8613–8622.

Synthesis and Properties of Organic Hexahalocerate(III) Salts
K. Pohako-Esko, T. Wehner, T. Bauer, P. S. Schulz, F. W. Heinemann, K. Müller-Buschbaum, P. Wasserscheid,
Eur. J. Inorg. Chem., 2016, 1333–1339.

Ionische Flüssigkeiten in der Synthese und Feinabstimmung von porösen Materialien: Wissensbasiertes Design von Eigenschaften durch einen kombinierten experimentellen und theoretischen Ansatz

A Molecular Level Understanding of Template Effects in Ionic Liquids
R. Elfgen, O. Hollo´czki, B. Kirchner,
Acc. Chem. Res., 2017, 50, 2949–2957.

Structural Investigations on Lithium-Doped Protic and Aprotic Ionic Liquids
P. Ray, T. Vogl, A. Balducci, B. Kirchner,
J. Phys. Chem. B, 2017, 121, 5279–5292.

First examples of organosilica-based ionogels: synthesis and electrochemical behavior
A. Taubert, R. Löbbicke, B. Kirchner, F. Leroux,
Beilstein J. Nanotechnol., 2017, 8, 736–751.

Theoretical Investigation of the Te4Br2 Molecule in Ionic Liquids
R. Elfgen, O. Hollóczki, P. Ray, M. F. Groh, M. Ruck, B. Kirchner,
Z. Anorg. Allg. Chem., 2017, 643, 41–52.

Ionic Liquid Induced Band Shift of Titanium Dioxide
H. Weber, B. Kirchner,
ChemSusChem, 2016, 9, 2505–2514.

Insights into Bulk Electrolyte Effects on the Operative Voltage of Electrochemical Double-Layer Capacitors
P. Ray, S. Dohm, T. Husch, C. Schütter, K. A. Persson, A. Balducci, B. Kirchner, M. Korth,
J. Phys. Chem. C, 2016, 120, 12325–12336.

Tuning the Carbon Dioxide Absorption in Amino Acid Ionic Liquids
D. S. Firaha, B. Kirchner,
ChemSusChem, 2016, 9, 1591–1599.

Insights into Bulk Electrolyte Effects on the Operative Voltage of Electrochemical Double-Layer Capacitors
P. Ray, S. Dohm, T. Husch, C. Schütter, K. A. Persson, A. Balducci, B. Kirchner, M. Korth,
J. Phys. Chem. C, 2016, 120, 12325–12336.

Complex Structural and Dynamical Interplay of Cyano-Based Ionic Liquids
H. Weber, B. Kirchner,
J. Phys. Chem. B, 2016, 120(9), 2471–2483.

Triphilic Ionic-Liquid Mixtures: Fluorinated and Nonfluorinated Aprotic Ionic-Liquid Mixtures
O. Hollóczki, M. Macchiagodena, H. Weber, M. Thomas, M. Brehm, A. Stark, O. Russina, A. Triolo, B. Kirchner,
ChemPhysChem, 2015, 16, 3325–3333.

En route formation of ion pairs at the ionic liquid–vacuum interface
F. Malberg, O. Hollóczki, M. Thomas, B. Kirchner,
Struct. Chem., 2015, 26, 1343–1349.

Toward an Accurate Modeling of Ionic Liquid-TiO2 Interfaces
H. Weber, M. Salanne, B. Kirchner,
J. Phys. Chem. C, 2015, 119, 25260–25267.

Domain Analysis in Nanostructured Liquids: A Post-Molecular Dynamics Study at the Example of Ionic Liquids
M. Brehm, H. Weber, M. Thomas, O. Hollóczki, B. Kirchner,
ChemPhysChem,  2015, 16, 3271–3277.

Ion pairing in ionic liquids
B. Kirchner, F. Malberg, D. S. Firaha, O. Hollóczki,
J. Phys.: Condens. Matter, 2015, 27, 463002.

Adsorption Behavior of the 1,3-Dimethylimidazolium Thiocyanate and Tetracyanoborate Ionic Liquids at Anatase (101) Surface
H. Weber, Th. Bredow, B. Kirchner,
J. Phys. Chem. C, 2015, 119 (27), 15137–15149.

Computer-Aided Design of Ionic Liquids as CO2 Absorbents
D. S. Firaha, O. Hollóczki, B. Kirchner,
Angew. Chem. Int. Ed., 2015, 54, 7805–7809.

Multiresolution Calculation of Ionic Liquids
B. Kirchner, O. Hollóczki, J. N. Canongia Lopes, A. A. H. Pádua,
WIREs Comput. Mol. Sci., 2015, 5, 202–214.

SO2 Solvation in the 1-Ethyl-3-Methylimidazolium Thiocyanate Ionic Liquid by Incorporation into the Extended Cation–Anion Network
D. S. Firaha, M. Kavalchuk, B. Kirchner,
J. Solution Chem., 2015, 44, 838–849.

Vorornoi dipole moments for the simulation of bulk phase vibrational spectra
M. Thomas, M. Brehm, B. Kirchner,
Phys. Chem. Chem. Phys., 2015, 17, 3207–3213.

Simulating the vibrational spectra of ionic liquid systems: 1-Ethyl-3-methylimidazolium acetate and its mixtures
M. Thomas, M. Brehm, O. Hollóczki, Z. Kelemen, L. Nyulászi, T. Pasinszki, B. Kirchner,
J. Chem. Phys., 2014, 024510.

On the origin of ionicity in ionic liquids. Ion pairing versus charge transfer
O. Hollóczki, F. Malberg, T. Welton, B. Kirchner,
Phys. Chem. Chem. Phys., 2014, 16, 16880–16890.

CO2 Absorption in the Protic Ionic Liquid Ethylammonium Nitrate
D. S. Firaha, B. Kirchner,
J. Chem. Eng. Data, 2014, 59 (10), 3098–3104.

Synthese neuartiger Cluster-Verbindungen früher Übergangsmetalle und mehrkerniger Verbindungen unter Verwendung ionischer Flüssigkeiten

New Hexanuclear Niobium Cluster Compounds with Perfluorinated Ligands Made Using Ionic Liquids
D. H. Weiß, F. Schröder, M. Köckerling,
Z. Anorg. Allg. Chem., 2017, 643, 345–351.
(selected for cover picture)

The Crystallization of Extended Niobium-Cluster Framework Compounds: A Novel Approach Using Ionic Liquids
A. Pigorsch, M. Köckerling,
Cryst. Growth Des., 2016, 16, 4240–4246.

Air-Stable, Well-Soluble AI2[Nb6Cl18] Cluster Compounds (AI = Organic Cation): A New Route for Preparation, Single-Crystal Structures, Properties, and ESI-Mass Spectra
J. König, I. Dartsch, A. Topp, E. Guillamón, R. Llusar, M. Köckerling,
Z. Anorg. Allg. Chem., 2016, 642, 572–578.

Easily Vaporizable Ionic Liquids – No Contradiction!
M. Köckerlin, T. Peppel, P. Thiele, S. P. Verevkin, V. N. Emel’yanenko, A. A. Samarov, W. Ruth,
Eur. J. Inorg. Chem., 2015, 4032–4037.

A New Mixed-Halide Copper Cyanido Complex and a New Copper(II) Acetato Complex, Prepared with an Ionic Liquid
A. Hinz, M. Köckerling,
Z. Anorg. Allg. Chem., 2015, 641, 1347–1351.

ILPIN: Ionische Flüssigkeiten als Vorläufer für anorganische Nanomaterialien

First examples of organosilica-based ionogels: synthesis and electrochemical behavior
A. Taubert, R. Löbbicke, B. Kirchner, F. Leroux,
Beilstein J. Nanotechnol., 2017, 8, 736–751.

Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties
K. Zehbe, M. Kollosche, S. Lardong, A. Kelling, U. Schilde, A. Taubert,
Int. J. Mol. Sci., 2016, 17(3), 391.

Materialien aus reduzierbaren Oxiden: Wissensbasierte Entwicklung neuer Tieftemperatur-Synthesemethoden

Pd-Mediated Ethylation of the Imidazolium Cation Monitored In-Operando on a SCILL-Type Catalyst
T. Bauer, V. Hager, M. Williams, M. Laurin, T. Döpper, A. Görling, N. Szesni, P. Wasserscheid, M. Haumann, J. Libuda,
ChemCatChem, 2017, 9,109 –113.

Ionic-Liquid-Modified Hybrid Materials Prepared by Physical Vapor Codeposition: Cobalt and Cobalt Oxide Nanoparticles in [C1C2Im][OTf] Monitored by In Situ IR Spectroscopy
S. Mehl, T. Bauer, O. Brummel, K. Pohako-Esko, P. Schulz, P. Wasserscheid, J. Libuda,
Langmuir, 2016, 32 (34), 8613–8622.

Synthesis and Properties of Organic Hexahalocerate(III) Salts
K. Pohako-Esko, T. Wehner, T. Bauer, P. S. Schulz, F. W. Heinemann, K. Müller-Buschbaum, P. Wasserscheid,
Eur. J. Inorg. Chem., 2016, 1333–1339.

In-situ IR spectroscopy of nanoparticle formation in ionic liquid films during physical vapor deposition of Pd
S. Mehl, T. Bauer, A. Toghan, O. Brummel, K. Pohako-Esko, P. Wasserscheid, J. Libuda,
Langmuir, 2015, 31, 12126.

Ligand interactions in ionic-liquid-modified electrocatalysts: in-situ IR-spectroscopy of methanol oxidation on Pt(111) in the presence of [C2C1Im][OTf]
F. Faisal, F. Lazarri, K. Pohako-Esko, P. Wasserscheid, J. Libuda,
Electrochimica Acta, 2016, 188, 825.

Interface Controls Spontaneous Crystallization in Thin Films of the Ionic Liquid [C2C1Im][OTf] on Atomically Clean Pd(111)
S. Schernich, V. Wagner, N. Taccardi, P. Wasserscheid, M. Laurin, J. Libuda,
Langmuir,  2014, 30, 6846.

Niedertemperatur-Synthesen von thermoelektrischen Materialien durch thermische Zersetzung von maßgeschneiderten metallorganischen Prekursoren in ionischen Flüssigkeiten

Improving the zT value of thermoelectrics by nanostructuring: Tuning the nanoparticle morphology of Sb2Te3 by ionic liquids
J. Schaumann, M. Loor, D. Ünal, A. Mudring, S. Heimann, U. Hagemann, S. Schulz, F. Maculewicz, G. Schierning,
Dalton Trans., 2017, 46, 656.
Inside front cover

Imidazolium Based Ionic Liquids: Impact of the Cation Symmetry and Alkyl Chain Length on the Enthalpy of Vaporization
A. V. Yermalayeu, D. H. Zaitsau, M. Loor, J. Schaumann, V. N. Emel’yanenko, S. Schulz, S. P. Verevkin,
Z. Anorg. Allg. Chem., 2017, 643, 81.

Synthesis of Sb2Se3 and Bi2Se3 Nanoparticles in Ionic Liquids at Low Temperatures and Solid State Structure of [C4C1Im]3[BiCl6]
M. Loor, G. Bendt, J. Schaumann, U. Hagemann, M. Heidelmann, Christoph Wölper, S. Schulz,
Z. Anorg. Allg. Chem., 2017, 643, 60.

Synthesis Bi2Te3 and (BixSb1-x)2¬Te3 Nanoparticles using the novel IL [C4mim]3[Bi3I12]
M. Loor, G. Bendt, U. Hagemann, C. Wölper, W. Assenmacher, S. Schulz,
Dalton Trans., 2016, 45, 15326.
Selected for Insight Back Cover

Record figure of merit values of highly stoichiometric Sb2Te3 porous bulk synthesized from tailor-made molecular precursors in ionic liquids
S. Heimann, S. Schulz, J. Schaumann, A. Mudring, J. Stötzel, G. Schierning,
J. Mater. Chem. C,  2015, 3, 10375–10380.

Wet-chemical Synthesis of different Bismuth Telluride Nanoparticles using Metal Organic Precursors - Single Source vs. Dual Source Approach
G. Bendt, A. Weber, S. Heimann, W. Assenmacher, O. Prymak, S. Schulz,
Dalton Trans., 2015, 44, 1472.

Synthesis of binary Sb2E3 (E = S, Se) and ternary Sb2(S,Se)3 Nanowires using tailor-made Single-Source-Precursors
S. Heimann, W. Assenmacher, O. Prymak, S. Schulz,
Eur. J. Inorg. Chem., 2015, 14, 2407.

Oxidative Addition of Diethylchalcogenanes to Lapperts Germylene and Stannylene
G. Bendt, S. Lapsien, P. Steiniger; D. Bläser, C. Wölper, S. Schulz,
Z. Anorg. Allg. Chem., 2015, 641, 797–802.

Syntheses and Solid State Structures of Et2SbTeEt and Et2BiTeEt
S. Heimann, A. Kuczkowski, D. Bläser, C. Wölper, R. Haak, G. Jansen, S. Schulz,
Eur. J. Inorg. Chem., 2014, 28, 4858.

Solid State Structures of Bis(diethylbismuthanyl)Sulfane, Selenane and Tellurane
S. Heimann, D. Bläser, C. Wölper, S. Schulz,
Organometallics,  2014, 33, 2295–2300.

The Bonding Situation in Triethylchalcogenostiboranes - Polarized Single Bond vs. Double Bond
S. Heimann, D. Bläser, C. Wölper, R. Haack, G. Jansen, S. Schulz,
Dalton Trans., 2014, 43, 14772–14777.

Von der Geburt bis zum Wachstum von metastabilen Metalloxiden in ionischen Flüssigkeiten

Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO2 in Ionic Liquids
P. Voepel, Ch. Seitz, J. M. Waack, St. Zahn, Th. Leichtweiß, A. Zaichenko, D. Mollenhauer, H. Amenitsch, M. Voggenreiter, S. Polarz, B. M. Smarsly,
Cryst. Growth Des, 2017, 17, 10, 5586–5601.

Synthesis of Titanium Oxide Nanostructures in Ionic Liquids
P. Voepel, B. M. Smarsly,
Z. Anorg. Allg. Chem., 2017, 643 (1), 3–13.

Low Temperature Reaction of Molecular Zinc Oxide Precursors in Ionic Liquids Leading to Ionogel Nanoparticles with Shape Anisotropy
M. Voggenreiter, P. Voepel, B. M. Smarsly, S. Polarz
Z. Anorg. Allg. Chem., 2017, 643 (1), 93–100.

Thermochemische Untersuchungen zu Phasenbildungsprozessen von Elementen und Verbindungen der Gruppe 15 und 16 bei Synthesen in ionischen Flüssigkeiten - Mechanismen der Auflösung, Strukturbildung und Abscheidung

Ionothermal Synthesis, Structure, and Bonding of the Catena-Heteropolycation (∞1)[Sb2 Se2]+
M. F. Groh, J. Breternitz, E. Ahmed, A. Isaeva, A. Efimova, P. Schmidt, M. Ruck,
Z. Anorg. Allg. Chem., 2015, 641, 388–393.

Thermal Stability and Crystallization Behavior of Imidazolium Halide Ionic Liquids
A. Efimova, G. Hubrig, P. Schmidt,
Thermochim. Acta., 2013, 573, 162.

Pseudohalogenchemie in ionischen Flüssigkeiten

Arsenic-Mediated C-C Coupling of Cyanides Leading to Cyanido Arsazolide [AsC4N4]-
S. Arlt, J. Harloff, A. Schulz, A. Stoffers, A. Villinger
Chem. - Eur. J., 2017, 23, 12735–12738.

Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles
V. N. Emel'yanenko, M. Kaliner, Th. Strassner, S. P. Verevkin
Fluid Phase Equilib., 2017, 433, 40–49.

Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles
D. H. Zaitsau, M. Kaliner, S. Lerch, Th. Strassner, V. N. Emel'yanenko, S. P. Verevkin
Z. Anorg. Allg. Chem., 2017, 643, 114–119.
Benchmarking thermochemical experiments and calculations of nitrogen-containing substituted adamantanes
V. N. Emel’yanenko, R. N. Nagrimanov, S. P. Verevkin,
J Therm Anal Calorim, 2017, 128, 1535–1546.

Cyanido Antimonate(III) and Bismuthate(III) Anions
S. Arlt, J. Harloff, A. Schulz, A. Stoffers, A. Villinger
Inorg. Chem., 2016, 55, 12321–12328.

Thermodynamic Analysis of Isomerization Equilibria of Chlorotoluenes and Dichlorobenzenes in a Biphasic Reaction Systems Containing Highly Acidic Chloroaluminate Melts
S. P. Verevkin, J. Messner, V. N. Emel'yanenko, M. G. Gantman, P. S. Schulz, P. Wasserscheid
J. Phys. Chem. B, 2016, 120 (51), 13152–13160.

Nicotinamides: evaluation of thermochemical experimental properties
A. A. Zhabina, R. N. Nagrimanov, V. N. Emel’yanenko, B. N. Solomonov, S. P. Verevkin,
J. Chem. Thermodynamics, 2016, 103, 69–75.

Structure–property relationships in halogenbenzoic acids: Thermodynamics of sublimation, fusion, vaporization and solubility
K.V. Zherikova, A.A. Svetlov, N.V. Kuratieva, S.P. Verevkin,
Chemosphere, 2016, 161, 157–166.

Benchmarking thermochemical experiments and calculations of nitrogen-containing substituted adamantanes
V. N. Emel’yanenko, R. N. Nagrimanov, S. P. Verevkin,
J Therm Anal Calorim, 2017, 128, 1535–1546.

Adamantanes: benchmarking of thermochemical properties
V. N. Emel´yanenko, R. N. Nagrimanov, B. N. Solomonov, S. P. Verevkin,
J. Chem. Thermodynamics, 2016, 101, 130–138.

Six-membered ring aliphatic compounds: structure-property relationships in phase transitions
R. N. Nagrimanov, B. N. Solomonov, V. N. Emel’yanenko, S. P. Verevkin,
Thermochimica Acta, 2016, 638, 80–88.

Benzoic acid and chlorobenzoic acids: Thermodynamic study of the pure compounds and binary mixtures with water
Th. Reschke, K. V. Zherikova, S. P. Verevkin, Ch. Held,
J. Pharm. Sci., 2016, 105, 1050–1058.

Carbonate Based Ionic Liquid Synthesis (CBILS®): Thermodynamic Analysis
R. St. Kalb, E. N. Stepurko, V. N. Emel’yanenko, S. P. Verevkin,
Thermodynamic Analysis PCCP, 2016, 18, 31904–31913.

Experimental and Theoretical Thermodynamic Study of Distillable Ionic Liquid [DBNH][OAc]
A. Ostonen, J. Bervas, P. Uusi-Kyyny, V. Alopaeus, Dz. H. Zaitsau, V. N. Emel’yanenko, Ch. Schick, A. W. T. King, J. Helminen, I. Kilpeläinen, A. A. Khachatrian, M. A. Varfolomeev, S. P. Verevkin,
Ind. Eng. Chem. Res., 2016, 55, 10445–10454.

Molecular E(CN)3 (E=Sb, Bi) Species Synthesized from Ionic Liquids as Solvates
S. Arlt, J. Harloff, A. Schulz, A. Stoffers, A. Villinger,
Chem. - Eur. J., 2016, 22, 16012–16016.

Lewis-Acid Catalyzed Synthesis of Cyanidoborate
K. Bläsing, S. Ellinger, J. Harloff, A. Schulz, K. Sievert, C. Täschler, A. Villinger, C. Zur Täschler,
Eur. J. Inorg. Chem., 2016, 8, 1175–1183.

Lewis-Acid Catalyzed Synthesis of Cyanidophosphates
K. Bläsing, S. Ellinger, J. Harloff, A. Schulz, K. Sievert, C. Täschler, A. Villinger, C. Zur Täschler,
Chem. - Eur. J., 2016, 12, 4175–4188.

Tetracyanido(difluorido)phosphates M+[PF2(CN)4]-
J. Bresien, S. Ellinger, J. Harloff, A. Schulz, K. Sievert, A. Stoffers, C. Täschler, A. Villinger, C. Zur Täschler,
Angew. Chem., 2015, 127, 4556–4559.
Angew. Chem. Int. Ed., 2015, 54, 4474–4477.

Structure-property relationships in Ionic Liquids: chain length dependence of the vaporization enthalpies of imidazolium-based ionic liquids with fluorinated substituents
D. H. Zaitsau, A. V. Yermalayeu, S. P. Verevkin, J. E. Bara, D. A. Wallace,
Thermochimica Acta, 2015, 622, 38–43.

Structure-property relationships in Ionic Liquids: influence of branched and cyclic groups on vaporization enthalpies of imidazolium-based ILs
Dz. H. Zaitsau, M. A. Varfolomeev, S. P. Verevkin, A. D. Stanton, M. S. Hindman, J. E. Bara,
J. Chem. Thermodyn., 2015, 93, 151–156.

Thermochemistry of ammonium based ionic liquids: thiocyanates—experiments and computations
A. V. Yermalayeu, Dz. H. Zaitsau, V. N. Emel’yanenko, S. P. Verevkin,
J. Solution Chem., 2015, 44 (3), 754–768.

Easily Vaporizable Ionic Liquids – No Contradiction!
M. Köckerling, T. Peppel, Ph. Thiele, S. P. Verevkin, V. N. Emel‘yanenko, A. A. Samarov, W. Ruth,
Eur. J. Inorg. Chem., 2015, 24, 4032–4037.

Zu dieser Seite

Alina Markova
Letzte Änderung: 09.06.2021