Publications
![Das Titelbild zeigt das Spiro-Dicuban Bi7S85+ in der Mitte, begleitet von zwei Bi4S44+ Heterocubanen auf beiden Seiten, die entlang ihrer Dreifachachse dargestellt sind. Diese Sulfidobismut-Polykationen wurden in Salzen mit [AlCl4]- und [S(AlCl3)3]2- Anio](https://tu-dresden.de/mn/chemie/ac/ac2/ressourcen/bilder/cover-galerie/chemistry-open_202102_p56/@@images/53711ae8-c6fa-4a53-8be7-4c39b4877919.jpeg)
Publications of the second funding period (2017 - 2020)
Molecular design and X-ray spectroscopy of & on iron nanocluster catalysts
|
Stereoselective Alkyne Hydrogenation by using a Simple Iron Catalyst |
|
Bimetallic Co/Al nanoparticles in an ionic liquid: synthesis and application in alkyne hydrogenation |
Base Metal Nanostructures via Ionic-Liquid-based Synthesis (BaseMet-IL)
|
Ge12{Fe(CO)3}8(µ-I)4: a germanium–iron cluster with Ge4, Ge2 and Ge units |
|
Ionic-Liquid-based Synthesis of the Bromine-rich Platinum Bromides [NBu3Me]2[Pt2Br10](Br2)2 and [NBu3Me]2[Pt2Br10](Br2)3 |
|
The Mixed Valence Iodine Chlorides [PCl4]2[ICl2][ICl4] and [BnMe3N]2[I2Cl3][ICl4] |
|
Bimetallic Nickel-Iridium and Nickel-Osmium Alloy Nanoparticles and Their Catalytic Performance in Hydrogenation Reactions |
|
Ionic-Liquid-Based Synthesis of the Germanium-Iron Carbonyls FeI4{GeI3Fe(CO)3}2 and (GeI3)2Fe(CO)4 |
Low-Temperature Conversions of Complex Solid Precursors in Ionic Liquids: New Compounds and Insights into Reaction Principles
|
Low-Temperature Ordering in the Cluster Compound (Bi8)Tl[AlCl4]3 |
|
Spontaneous Substitutions on Phosphorus Trihalides in Imidazolium Halide Ionic Liquids: A Grotthuss Diffusion of Anions? |
|
Low-temperature tailoring of copper-deficient Cu3-xP – electric properties, phase transitions and performance in Li ion batteries |
|
The Intermetalloid Cluster Cation (CuBi8)3+ |
|
Understanding the Chemical Reactivity of Phosphonium-Based Ionic Liquids with Tellurium |
|
Mechanistic exploration of the copper(I) phosphide synthesis in phosphonium-based and phosphorus-free ionic liquids |
|
Dissolution behaviour and activation of selenium in phosphonium based ionic liquids |
|
On the Anion Exchange of PX3 (X = Cl, Br, I) in Ionic Liquids comprising Halide Anions |
Preparation of intermetallic phases in ionic liquids
|
Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids |
Low-Temperature Approach to Solvent-Free Chalcogenidometalate Materials
|
Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles |
|
Synthesis and Structures of Compounds with Molecular, One-Dimensional or Two-Dimensional Selenido Cadmate Anions |
|
K2Hg2Te3 – Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material |
|
Formation of [(CnC1imTe)4Hg]2+ (n = 6, 8) upon In-Situ Generation of Dialkylimidazole-2-Tellurones in Ionic Liquids at Room Temperature |
|
F(C4C1Im)6[Hg7Se10]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids |
|
Multi-Valent Group 14 Chalcogenide Architectures from Ionic Liquids: 0-{[Cs@SnII4(GeIV4Se10)4]7-} and 2D-{[SnII(GeIV4Se10)]2-} |
|
[Hg4Te8(Te2)4]8–: A Heavy Metal Porphyrinoid Embedded in a Lamellar Structure |
|
The Role of [BF4]- and [B(CN)4]- Anions in the Ionothermal Synthesis of Chalcogenidometalates |
|
Exploring the Chemical Reaction Space at the Formation of Chalcogenidometalate Superspheres in Ionic Liquids |
|
Crystalline Chalcogenido Metalates – Synthetic Approaches for Materials Synthesis and Transformation |
Synthesis of intermetallic transition metal-main group metal nanoparticles in ionic liquids
|
Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids |
|
Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand |
|
Synthesis of Rare Earth Metal and Rare Earth Metal Fluoride Nanoparticles in Ionic Liquids and Propylene Carbonate |
|
Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles |
|
Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety |
|
Synthesis of metal-fluoride nanoparticles supported on thermally reduced graphite oxide |
Multifunctional Soft Materials from and with Borate Ionic Liquids and Lanthanides
|
Perfluoroalkyltricyanoborate and Perfluoroalkylcyanofluoroborate Anions: Building Blocks for Low-viscosity Ionic Liquids |
|
Chlorocyanoborates: Synthesis, Spectroscopic and Structural Characterization, and Properties of Ionic Liquids |
|
The Role of [BF4]– and [B(CN)4]– Anions in the Ionothermal Synthesis of Chalcogenidometalates |
|
Lanthanide Coordination Polymers and MOFs Based on the Dicyanodihydridoborate Anion |
|
Transformation of [EMIm][BPB] into a Cationic Luminescent Ln-Coordination Polymer with the Bis(phthalato)borate Anion |
Solubility of molecular and ionic precursors in ionic liquids
|
Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids |
|
Vaporization thermodynamics of ionic liquids with tetraalkylphosphonium cations |
|
Thermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles |
|
Hydrogen bonding of molecular solutes in protic and aprotic ionic liquids |
|
Thermochemistry of drugs: experimental and theoretical study of analgesics |
|
Energetic structure-property relationships in thermochemistry of halogenosubstituted benzoic acids |
|
Thermodynamics and proton activities of protic ionic liquids with quantum cluster equilibrium theory |
|
Imidazolium based ionic liquids containing methanesulfonate anion: comprehensive thermodynamic study |
|
Substituted benzamides and substituted benzoic acids: like tree, like fruit? |
|
Imidazolium based ionic liquids containing trifluoroacetate anion: comprehensive thermodynamic study |
|
Solubility predictions of acetanilide derivatives in water: Combining thermochemistry and thermodynamic modeling |
|
Thermodynamics of Imidazolium-Based Ionic Liquids Containing the Trifluoromethanesulfonate Anion |
|
Melting temperature and heat of fusion of cytosine revealed from fast scanning calorimetry |
|
Carbonate Based Ionic Liquid Synthesis (CBILS®): Development of Continuous Flow Method for Preparation of Ultra-Pure Ionic Liquids |
|
Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles |
Understanding solution based syntheses of inorganic materials in ionic liquids: Peering into the reaction mechanism from birth to age
|
Strong Microheterogeneity in Novel Deep Eutectic Solvents |
|
Ionothermal synthesis of crystalline microporous aluminophosphates: Systematic study on the conditions affecting the framework type |
|
Molecular Dynamics Simulations of Lithium Doped Ionic-Liquid Electrolytes |
|
Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO2 in Ionic Liquids |
|
Photocatalytic activity of multiphase TiO2(B)/anatase nanoparticle heterojunctions prepared from ionic liquids |
|
Hydrophilic Ionic Liquid Mixtures of Weakly and Strongly Coordinating Anions with and without Water |
|
How to harvest Grotthuss diffusion in protic ionic liquid electrolyte systems |
|
Thermodynamics and proton activities of protic ionic liquids with quantum cluster equilibrium theory |
|
Structure and lifetimes in ionic liquids and their mixtures |
|
A Molecular Level Understanding of Template Effects in Ionic Liquids |
New Early Transition Metal Atom Cluster Materials: In and with Ionic Liquids
ILPIN: Ionic Liquid Precursors for Multicomponent Inorganic Nanomaterials
|
The crystal structure of N-butylpyridinium bis(µ2-dichlorido)-tetrachloridodicopper(II), C18H28N2Cu2Cl6 |
|
The ionic liquid [Bmim][FeCl4] catalyzes the formation of iron doped mesoporous silica aerogels for H2O2 decomposition |
|
CuS nanoplates from ionic liquid precursors—Application in organic photovoltaic cells |
|
Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior |
Low-temperature Synthesis of Thermoelectric Materials by Thermal Decomposition of Tailor-made Precursors in Ionic Liquids
|
Ionic Liquid-Based Low-Temperature Synthesis of Phase-Pure Tetradymite-Type Materials and Their Thermoelectric Properties |
Thermochemical investigations of phase formation processes of elements and compounds of group 15 and 16 in ionic liquid based synthesis - Mechanism of dissolution, structure formation and precipitation
|
Low-Temperature Ordering in the Cluster Compound (Bi8)Tl[AlCl4]3 |
Pseudohalogen Chemistry in Ionic Liquids with Non-innocent Cations and Anions
| Salts of HCN-Cyanide Aggregates: [CN(HCN)2]- and [CN(HCN)3]-
K. Bläsing, J. Harloff, A. Schulz, A. Stoffers, P. Stoer, A. Villinger, |
| Hexacyanidosilicates with Functionalized Imidazolium Counterions
J. Harloff, K. C. Laatz, S. Lerch, A. Schulz, P. Stoer, T. Strassner, A. Villinger, |
|
Pseudo Halide Chemistry in Ionic Liquids with Decomposable Anions |
|
Heavy Neutral and Anionic Pnictogen Thiocyanates |
|
Cyanidosilicates – Synthesis and Structure |
Chalcogenide-based Ionic Liquids in the Synthesis of Metal Chalcogenide and Interchalcogenide Materials near Room Temperature
Publications of the first funding period (2014 - 2017)
Intermetallic Clusters and Nanoparticles
Ionic Liquids as Size- and Shape-Regulating Solvents for the Synthesis of Cobalt Nanoparticles
S. Essig, S. Behrens,
Chem. Ing. Tech. 2015, 87, 1741–1747.
[(Pb6I8){Mn(CO)5}6]2– – an Octahedral (M6Xn)-like Cluster with Unprecedented Inverted Bonding
S. Wolf, K. Reiter, F. Weigend, W. Klopper, C. Feldmann,
Inorg. Chem. 2015, 54, 3989–3994
Electrochemical Synthesis of Gallium and Indium Nanostructures and their Oxides/Nitrides with Ionic Liquids and Physical Surface Modification
|
Electroless Deposition of III-V Semiconductor Nanostructures from Ionic Liquids at Room Temperature |
|
Electrodeposition of GaN in the Presence of NH4Cl in an Ionic Liquid: Hints for GaN Formation |
Low-Temperature Conversions of Complex Solid Precursors in Tailored Ionic Liquids: New Compounds and Insights into Reaction Principles
|
Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles |
|
Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles |
|
An Amorphous Phase of Zinc and Silicon at Composition Zn2Si5 (:H, OH) |
|
Redox Route from Inorganic Precursor Li2C2 to Nanopatterned Carbon |
|
Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids |
|
Controlled Synthesis of Pnicogen–Chalcogen Polycations in Ionic Liquids |
|
Resource-Efficient High-Yield Ionothermal Synthesis of Microcrystalline Cu3–xP |
|
Polyhedral Bismuth Polycations Coordinating Gold(I) with Varied Hapticity in a Homoleptic Heavy-Metal Cluster |
|
Unexpected Reactivity of Red Phosphorus in Ionic Liquids |
|
[P3Se4]+ – a Binary Phosphorus Selenium Cation |
|
Ionothermal Synthesis, Structure, and Bonding of the Catena-Heteropolycation (∞1)[Sb2 Se2]+ |
|
Bi2S3 Bipyramids in Layered Sulfides M2Bi2S3(AlCl4)2 (M = Ag, Cu) |
|
[Sb7Se8Br2]3+ and [Sb13Se16Br2]5+ – Double and Quadruple Spiro Cubanes from Ionic Liquids |
|
Substitution of Conventional High–Temperature Syntheses of Inorganic Compounds by Near–Room |
Low-Temperature Approach to Solvent-Free Chalcogenidometallate Materials
Intermetallic Nanoparticle Synthesis in Ionic Liquids
Multifunctional Soft Materials from and with Borate Ionic Liquids and Lanthanides
|
Homoleptic Luminescent Lanthanide Frameworks with the Tricyanohydridoborate Anion |
|
Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion |
|
Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions |
|
Cover Picture: Protonation versus Oxonium Salt Formation: Basicity and Stability Tuning of Cyanoborate Anions |
|
Deprotonation of a Hydridoborate Anion |
|
Bis(salicylato)borate as Versatile Sensitizer for Highly Luminescent Lanthanide Oxoborates from the Ultraviolet to Near Infrared with 4f and 5d Participation of the Lanthanides |
|
Syntheses and Structures of New Rare-Earth Metal Tetracyanidoborates |
|
Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates |
|
Protonation Versus Oxonium Salt Formation – Basicity and Stability Tuning of Cyanoborate Anions |
|
Anhydrous, Homoleptic Lanthanide Frameworks with the Pentafluoroethyltricyanoborate Anion |
|
Unexpected Dimeric Spiro-Borate Complexes from Lewis-Acid Induced Transformation of Oxalatoborates |
|
Synthesis and Properties of Organic Hexahalocerate(III) Salts |
|
The Hexacyanodiborane(6) Dianion [B2(CN)6]2- |
|
18[Pr(BSB)3(py)2]: A Lanthanide Bis(salicylato)borate at the Junction between Solvothermal and Ionothermal Conditions |
Synthesis of Novel MOF Materials from Structured and Functionalized Ionic Liquid Media
|
Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor |
|
Ionic-Liquid-Modified Hybrid Materials Prepared by Physical Vapor Codeposition: Cobalt and Cobalt Oxide Nanoparticles in [C1C2Im][OTf] Monitored by In Situ IR Spectroscopy |
|
Synthesis and Properties of Organic Hexahalocerate(III) Salts |
Ionic Liquids in the Synthesis and Tuning of Porous Materials: Knowledge-Based Design of Properties Using a Combined Experimental and Theoretical Approach
|
A Molecular Level Understanding of Template Effects in Ionic Liquids |
|
Structural Investigations on Lithium-Doped Protic and Aprotic Ionic Liquids |
|
First examples of organosilica-based ionogels: synthesis and electrochemical behavior |
|
Theoretical Investigation of the Te4Br2 Molecule in Ionic Liquids |
|
Ionic Liquid Induced Band Shift of Titanium Dioxide |
|
Insights into Bulk Electrolyte Effects on the Operative Voltage of Electrochemical Double-Layer Capacitors |
|
Tuning the Carbon Dioxide Absorption in Amino Acid Ionic Liquids |
|
Insights into Bulk Electrolyte Effects on the Operative Voltage of Electrochemical Double-Layer Capacitors |
|
Complex Structural and Dynamical Interplay of Cyano-Based Ionic Liquids |
|
Triphilic Ionic-Liquid Mixtures: Fluorinated and Nonfluorinated Aprotic Ionic-Liquid Mixtures |
|
En route formation of ion pairs at the ionic liquid–vacuum interface |
|
Toward an Accurate Modeling of Ionic Liquid-TiO2 Interfaces |
|
Domain Analysis in Nanostructured Liquids: A Post-Molecular Dynamics Study at the Example of Ionic Liquids |
|
Ion pairing in ionic liquids |
|
Adsorption Behavior of the 1,3-Dimethylimidazolium Thiocyanate and Tetracyanoborate Ionic Liquids at Anatase (101) Surface |
|
Computer-Aided Design of Ionic Liquids as CO2 Absorbents |
|
Multiresolution Calculation of Ionic Liquids |
|
SO2 Solvation in the 1-Ethyl-3-Methylimidazolium Thiocyanate Ionic Liquid by Incorporation into the Extended Cation–Anion Network |
|
Vorornoi dipole moments for the simulation of bulk phase vibrational spectra |
|
Simulating the vibrational spectra of ionic liquid systems: 1-Ethyl-3-methylimidazolium acetate and its mixtures |
|
On the origin of ionicity in ionic liquids. Ion pairing versus charge transfer |
|
CO2 Absorption in the Protic Ionic Liquid Ethylammonium Nitrate |
New Transition Metal Atom Cluster/Polynuclear Materials: In and with Ionic Liquids
ILPIN: Ionic Liquid Precursors for Multicomponent Inorganic Nanomaterials
|
First examples of organosilica-based ionogels: synthesis and electrochemical behavior |
|
Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties |
Reducible Oxide Materials: Knowledge-Driven Design of Novel Low-Temperature Synthesis Routes
|
Pd-Mediated Ethylation of the Imidazolium Cation Monitored In-Operando on a SCILL-Type Catalyst |
|
Ionic-Liquid-Modified Hybrid Materials Prepared by Physical Vapor Codeposition: Cobalt and Cobalt Oxide Nanoparticles in [C1C2Im][OTf] Monitored by In Situ IR Spectroscopy |
|
Synthesis and Properties of Organic Hexahalocerate(III) Salts |
|
In-situ IR spectroscopy of nanoparticle formation in ionic liquid films during physical vapor deposition of Pd |
|
Ligand interactions in ionic-liquid-modified electrocatalysts: in-situ IR-spectroscopy of methanol oxidation on Pt(111) in the presence of [C2C1Im][OTf] |
|
Interface Controls Spontaneous Crystallization in Thin Films of the Ionic Liquid [C2C1Im][OTf] on Atomically Clean Pd(111) |
Low-Temperature Synthesis of Thermoelectric Materials by Thermal Decomposition of Tailor-Made Metal Organic Precursors in Ionic Liquids
|
Improving the zT value of thermoelectrics by nanostructuring: Tuning the nanoparticle morphology of Sb2Te3 by ionic liquids |
|
Imidazolium Based Ionic Liquids: Impact of the Cation Symmetry and Alkyl Chain Length on the Enthalpy of Vaporization |
|
Synthesis of Sb2Se3 and Bi2Se3 Nanoparticles in Ionic Liquids at Low Temperatures and Solid State Structure of [C4C1Im]3[BiCl6] |
|
Synthesis Bi2Te3 and (BixSb1-x)2¬Te3 Nanoparticles using the novel IL [C4mim]3[Bi3I12] |
|
Record figure of merit values of highly stoichiometric Sb2Te3 porous bulk synthesized from tailor-made molecular precursors in ionic liquids |
|
Wet-chemical Synthesis of different Bismuth Telluride Nanoparticles using Metal Organic Precursors - Single Source vs. Dual Source Approach |
|
Synthesis of binary Sb2E3 (E = S, Se) and ternary Sb2(S,Se)3 Nanowires using tailor-made Single-Source-Precursors |
|
Oxidative Addition of Diethylchalcogenanes to Lapperts Germylene and Stannylene |
|
Syntheses and Solid State Structures of Et2SbTeEt and Et2BiTeEt |
|
Solid State Structures of Bis(diethylbismuthanyl)Sulfane, Selenane and Tellurane |
|
The Bonding Situation in Triethylchalcogenostiboranes - Polarized Single Bond vs. Double Bond |
From Birth to Growth of Metastable Metal Oxides in Ionic Liquids
|
Peering into the Mechanism of Low-Temperature Synthesis of Bronze-type TiO2 in Ionic Liquids |
|
Synthesis of Titanium Oxide Nanostructures in Ionic Liquids |
|
Low Temperature Reaction of Molecular Zinc Oxide Precursors in Ionic Liquids Leading to Ionogel Nanoparticles with Shape Anisotropy |
Thermochemical Investigations of Phase Formation Processes of Elements and Compounds of Group 15 and 16in IL (Ionic Liquid) Based Synthesis - Mechanism of Dissolution, Structure Formation and Precipitation
|
Ionothermal Synthesis, Structure, and Bonding of the Catena-Heteropolycation (∞1)[Sb2 Se2]+ |
|
Thermal Stability and Crystallization Behavior of Imidazolium Halide Ionic Liquids |
Pseudohalogen Chemistry in Ionic Liquids
|
Arsenic-Mediated C-C Coupling of Cyanides Leading to Cyanido Arsazolide [AsC4N4]- |
|
Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles |
|
Thermochemical Properties of Tunable Aryl Alkyl Ionic Liquids (TAAILs) based on Phenyl-1H-imidazoles |
|
Cyanido Antimonate(III) and Bismuthate(III) Anions |
|
Thermodynamic Analysis of Isomerization Equilibria of Chlorotoluenes and Dichlorobenzenes in a Biphasic Reaction Systems Containing Highly Acidic Chloroaluminate Melts |
|
Benchmark Thermodynamic Properties of Methyl- and Methoxy-Benzamides: Comprehensive Experimental and Theoretical Study |
|
Nicotinamides: evaluation of thermochemical experimental properties |
|
Structure–property relationships in halogenbenzoic acids: Thermodynamics of sublimation, fusion, vaporization and solubility |
|
Benchmarking Thermochemical Experiments and Calculations of Nitrogen Containing Substituted Adamantanes |
|
Adamantanes: benchmarking of thermochemical properties |
|
Six-membered ring aliphatic compounds: structure-property relationships in phase transitions |
|
Benzoic acid and chlorobenzoic acids: Thermodynamic study of the pure compounds and binary mixtures with water |
|
Carbonate Based Ionic Liquid Synthesis (CBILS®): Thermodynamic Analysis |
|
Experimental and Theoretical Thermodynamic Study of Distillable Ionic Liquid [DBNH][OAc] |
|
Molecular E(CN)3 (E=Sb, Bi) Species Synthesized from Ionic Liquids as Solvates S. Arlt, J. Harloff, A. Schulz, A. Stoffers, A. Villinger, |
|
Lewis-Acid Catalyzed Synthesis of Cyanidoborate |
|
Lewis-Acid Catalyzed Synthesis of Cyanidophosphates |
|
Tetracyanido(difluorido)phosphates M+[PF2(CN)4]- |
|
Structure-property relationships in Ionic Liquids: chain length dependence of the vaporization enthalpies of imidazolium-based ionic liquids with fluorinated substituents |
|
Structure-property relationships in Ionic Liquids: influence of branched and cyclic groups on vaporization enthalpies of imidazolium-based ILs |
|
Thermochemistry of ammonium based ionic liquids: thiocyanates—experiments and computations |
|
Easily Vaporizable Ionic Liquids – No Contradiction! |