Volodymyr Bon

Wissenschaftlicher Mitarbeiter

Herr Dr. rer. nat. Volodymyr Bon

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Professur f. Anorganische Chemie I

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Besuchsadresse:

Chemie/Hydrowissenschaften, Raum 468 Bergstraße 66

01069 Dresden

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FORSCHUNGSINTERESSEN:

Synthese neuer starrer und flexibler MOFs für die Gasspeicherung und Gastrennung;
Charakterisierung von MOFs mittels Röntgendiffraktometrie an Einkristallen und Pulvern, Physisorption von Gasen, Gasgemischen und Dämpfen;
Untersuchung der Flexibilität in schaltbaren MOFs mittels Gassorption und in situ XRD Methoden;
Entwicklung von Instrumenten am Synchrotron für in situ Röntgenpulverdiffraktometrie und Physisorption an schaltbaren MOFs.
Untersuchung der Kinetik von Phasenumwandlungen in flexiblen MOFs mittels in situ Röntgenpulverdiffraktometrie am Synchrotron.

ABGESCHLOSSENE PROJEKTE:

BMBF Projekt 05K13OD3 „Untersuchungen von dynamischen Wirt-Gast Wechselwirkungen an flexiblen porösen Materialien via in situ EXAFS, XANES und Einkristalldiffraktometrie“ 2013 – 2016;
BMBF Projekt 05K16OD1 „Instrumentierung zu mechanistischen in situ Untersuchungen von adsorptiven Wärmespeicher- und Trennverfahren“, 2016 – 2019;
BMBF Projekt 05K19OD2 „Instrumentierung für in situ Röntgenpulverdiffraktometrie an schaltbaren nanoporösen Feststoffen parallel zur Anwendung von chemischen und elektromagnetischen Stimuli“, 2019 – 2022;
Assoziierter Forscher in DFG-ANR Projekt "Grundlagen der negativen Gasadsorption in mesoporösen Festkörpern: Auf dem Weg zu schwellenwert-sensitiven mechanischen Aktuatoren", 2019-2021;
Assoziierter Forscher in DFG FOR2433 „MOF switches“ (in situ PXRD, Einkristalldiffraktometrie), 2017-2023;
AMPLIPORE „Understanding negative gas adsorption in highly porous networks for the design of pressure-amplifying materials“ (Gruppenleiter, in situ Röntgenpulverdiffraktometrie, Einkristalldiffraktometrie), 2018-2023;
ERC Proof of Concept Grant “A discovery tool for accelerated adsorption-diffraction analysis of dynamic adsorbents in gas separation”, 2021-2022.

LAUFENDE PROJEKTE:

BMBF Projekt 05K22OD1 „TIMESWITCH“: „Instrumentierung für zeitaufgelöste röntgenpulverdiffraktometrische Untersuchungen von adsorptionsinduziertem Schalten in kristallinen nanoporösen Materialien“ 2022-2025
BMBF Projekt 05K22OD2 „TOMOPORE“: „Multizweck Instrumentierung für das Monitoring von Fluiddynamik in nanoporösen Feststoffen mittels in situ Röntgenkryotomographie und röntgenspektroskopischen Methoden“ 2022 - 2025
DFG KA1698/41-1 „Der Vortrieb von Charakterisierung der Gerüstverbindungen mittels Positron Annihilation Spektroskopie (PAS)” 2022 - 2025

LEHRTÄTIGKEIT:

Vorlesungen „Allgemeine und anorganische Chemie“ (Modul VNT-03) für die Studiengang „Verfahrenstechnik und Naturstofftechnik“.
Betreuung von Bachelor- und Masterarbeiten.

BUCHKAPITEL:

V. Bon, K. Roztocki, P. Iacomi, C. L. Hobday, I. Senkovska, A. Pöppl, E. Brunner, S. Kaskel: The dynamic view: Multiscale Characterization Techniques for Flexible Frameworks. Flexible Metal-Organic Frameworks: Structural Design, Synthesis and Properties, edited by Susumu Kitagawa, 2024, ISBN: 978-1-83916-452-1.
S. Kaskel, S. Ehrling, I. Senkovska, V. Bon, K. D. Ngyuen, H. Miura: Flexibility and Switchable Porosity in Metal-Organic Frameworks: Phenomena, Characterization and Functions. Comprehensive Coordination Chemistry III, edited by Cameron Kepert, Elsevier, 2021, ISBN: 9780081026885.
V. Bon, I. Senkovska, S. Kaskel: Metal-Organic Frameworks. Nanoporous Materials for Gas Storage. Nanoporous Materials for Gas Storage, Edited by Katsumi Kaneko and Francisco Rodríguez-Reinoso, 2019, ISBN: 978-981-13-3503-7.
I. Senkovska, V. Bon: In Situ X-ray Diffraction and XAS Methods. The Chemistry of Metal-Organic Frameworks: Synthesis, Characterization, and Applications, Edited by Stefan Kaskel, 2016, ISBN: 9783527338740.

PATENTE:

V. Bon, V. Romaka, S. Kaskel, Adsorption chamber with removable sample holders for X-ray measurements, 00017P0392DEEP, 2022.
V. Bon, V. Romaka, S. Kaskel, Adsorption chamber system for X-ray measurements, 2021110815333300DE, 2021.
K. Eckhardt, J. Grothe, F. M. Wisser, J. Getzschmann, V. Bon and S. Kaskel, Lead-free light-absorbing compounds as components for organic and hybrid perovskite-type solar cells and optoelectronic devices, processes for production thereof, DE102015213100A1, 2017.

PUBLIKATIONEN:

2024

A. Subanbekova, A. A. Bezrukov, V. Bon, V. I. Nikolayenko, K. Koupepidou, D. Sensharma, S. J. Nikkhah, S.-Q. Wang, S. Kaskel, M. Vandichel, M. J. Zaworotko, Effect of Polymorphism on the Sorption Properties of a Flexible Square-Lattice Topology Coordination Network, ACS Appl. Mater. Interfaces, 2024, accepted manuscript.
A. Rubio-Gaspar, A. Misturini, R. Millán, N. Almora-Barrios, S. Tatay, V. Bon, M. Bonneau, V. Guillerm, M. Eddaoudi, S. Navalón, S. Kaskel, D. Armentano, C. Marti-Gastaldo, Translocation and confinement of tetraamines in adaptable microporous cavities, Angew. Chem. Int. Ed., 2024, e202402973.
A.G. Attallah, V. Bon, K. Maity, R. Zaleski, E. Hirschmann, S. Kaskel, A. Wagner, Revisiting Metal–Organic Frameworks Porosimetry by Positron Annihilation: Metal Ion States and Positronium Parameters, J. Phys. Chem. Lett., 2024, 15, 4560-4567.
S.-Q. Wang, V. Bon, S. Darwish, S.-M. Wang, Q.-Y. Yang, Z. Xu, S. Kaskel, M. J. Zaworotko, Insight into the Gas-Induced Phase Transformations in a 2D Switching Coordination Network via Coincident Gas Sorption and In Situ PXRD, ACS Materials Lett., 2024, 6, 666–673.
K. D. J. Hindricks, V. Bon^*, O. Treske, A. Hannebauer, A. Schaate, Y. Krysiak, S. Kaskel, Guest-Induced Flexibility in a Multifunctional Ruthenium-based Metal-Organic Framework, Chem. Mater., 2024, 36, 2, 657–665.

2023

R. Bose, V. Bon, N. Bönisch, P. Selvam, N. S. Kaisare, S. Kaskel, Crystal Size Dependent Flexibility in ZIF-7: From Macro-to Nanoscale, Chem. Mater., 2023, 35, 18, 7825–7838.
A.G. Attallah, V. Bon^*, K. Maity, E. Hirschmann, M. Butterling, A. Wagner, S. Kaskel, Unravelling the Water Adsorption Mechanism in Hierarchical MOFs: Insights from In Situ Positron Annihilation Lifetime Studies, ACS Applied Mater. Interfaces, 2023, 15, 41, 48264–48276.
B. Felsner, K. Gopalsamy, V. Bon, I. Senkovska, G. Maurin, S. Kaskel, Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd‐Numbered Ring‐Expanded Linkers, Small Science, 2023, 3, 2300158.
M. F. Lukman, M. Mendt, V. Bon, S. Kaskel, A. Pöppl, Selective Adsorption of Dihydrogen Isotopes on DUT-8 (Ni, Co) Monitored by In Situ Electron Paramagnetic Resonance, Chem. Commun., 2023, 59, 9884-9887.
A. Hoffman, I. Senkovska, L. Abylgazina, V. Bon, V. Grzimek, A.M. Dominic, M. Russina, M.A. Kraft, I. Weidinger, W. Zeier, V. Van Speybroeck, S. Kaskel, The role of phonons in switchable MOFs: A model material perspective, J. Mater. Chem. A, 2023, Advance Article.
K. Roztocki, W. Gromelska, F. Formalik, A. Giordana, L. Andreo, G. Mahmoudi, V. Bon, S. Kaskel, L.J. Barbour, A. Janiak, Shape-Memory Effect Triggered by π–π Interactions in a Flexible Terpyridine Metal–Organic Framework, ACS Mater. Lett., 2023, 5, 1256-1260.
F. Walenszus, V. Bon, J.D. Evans, S. Krause, J. Getzschmann, S. Kaskel, M. Dvoyashkin, On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks, Nat. Commun., 2023, 14, 1, 3223.
K. Maity, V. Bon, S. Kaskel, Toward Controlled Partial Desolvation of Guest-Responsive Metal–Organic Frameworks for Precise Porosity Control, Chem. Mater., 2023, 35, 11, 4192–4200.
V. Bon, Exploring the guest-induced structural dynamics in MOFs by in situ PXRD techniques, Acta Cryst. A, 2023, 78, a193-a193.
I. Senkovska, V. Bon, L. Abylgazina, M. Mendt, J. Berger, G. Kieslich, P. Petkov, J. Fiorio, J.O. Joswig, T. Heine, L. Schaper, C. Bachetzky, R. Schmid, R. A. Fischer, A. Pöppl, E. Brunner, S. Kaskel Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System, Angew. Chem. Int. Ed., 2023, e202218076.
A. Subanbekova, V.I. Nikolayenko, A.A. Bezrukov, D. Sensharma, N. Kumar, D.J. O'Hearn, V. Bon, S.Q. Wang, K. Koupepidou, S. Darwish, S. Kaskel, M. J. Zaworotko, Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal–organic framework, J. Mater. Chem. A, 2023, 11, 17, 9691-9699.
A. De, S. Haldar, S. Michel, L. Shupletsov, V. Bon, N. Lopatik, L. Ding, L. Eng, G. Auernhammer, E. Brunner, A. Schneemann, Manipulation of Covalent Organic Frameworks by Side-Chain Functionalization: Toward Few Layer Nanosheets, Chem. Mater., 2023, 35,10,3911-3922.
B. Felsner, V. Bon, C. Bachetzky, E. Brunner, S. Kaskel, Isoreticular design of flexible Zn-based tetracarboxylate MOFs, Inorg. Chem. Front., 2023, 10, 11, 3237-3247.
M. Maliuta, I. Senkovska, V. Romaka, M. Roslova, Z. Huang, P. Petkov, V. Bon, S. Kaskel, Flexibility in DUT-8(Cu) metal-organic framework: impact of cluster, stress, history, and hierarchical texture, CCS Chemistry, 2023, 1-30.
K. Thangavel, F. Walenszus, M. Mendt, V. Bon, S. Kaskel, A. Pöppl, Monitoring the Local Structure and Magnetic Properties of the Dinuclear Cu2-Paddle Wheel Nodes in the Mesoporous Metal–Organic Framework, DUT-49 (Cu), upon Adsorption-Induced Breathing Transitions, J. Phys. Chem. C, 2023, 127, 8217-8234.
K. Thangavel, M. Mendt, B. Garai, A. Folli, V. Bon, D. M. Murphy, S. Kaskel, A. Pöppl, Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy, AIP Adv., 2023, 13, 1, 015019.
S. Haldar, P. Bhauriyal, A.R. Ramuglia, A.H. Khan, S. De Kock, Sunel; A. Hazra, V. Bon, D.L. Pastoetter, S. Kirchhoff, L. Shupletsov, Sulfide‐Bridged Covalent Quinoxaline Frameworks for Lithium–Organosulfide Batteries, Adv. Mater., 2023, 2210151.
M. Maliuta, I. Senkovska, R. Thümmler, S. Ehrling, S. Becker, V. Romaka, V. Bon, J.D. Evans, S. Kaskel, Particle size-dependent flexibility in DUT-8(Cu) pillared layer metal–organic framework, Dalton Trans., 2023, 52, 9, 2816-2824.
Y. Jiang, Y. Liu, S. Grosjean, V. Bon, P. Hodapp, A.B. Kanj, S. Kaskel, S. Bräse, C. Wöll, L. Heinke, Substrate‐Bound Diarylethene‐Based Anisotropic Metal‐Organic Framework Films as Photoactuators with a Directed Response, Angew. Chem. Int. Ed., 2023, e202218052.
H. Miura, V. Bon, I. Senkovska, S. Ehrling, N. Bönisch, G. Mäder, S. Grünzner, A. Khadiev, D. Novikov, K. Maity, A. Richter, S. Kaskel Spatiotemporal Design of the Metal‐Organic Framework DUT‐8(M) Adv. Mater., 2023, 35, 2207741.

2022

K. Roztocki, V. Bon, I. Senkovska, D. Matoga, S. Kaskel A Logic Gate Based on a Flexible Metal–Organic Framework (JUK‐8) for the Concomitant Detection of Hydrogen and Oxygen Chem. Eur. J., 2022, 28, e202202255.
S. Ehrling, I. Senkovska, A. Efimova, V. Bon, L. Abylgazina, P. Petkov, J. D. Evans, A. G. Attallah, M. Th. Wharmby, M. Roslova, Z. Huang, H. Tanaka, A. Wagner, P. Schmidt, S. Kaskel Temperature Driven Transformation of the Flexible Metal–Organic Framework DUT‐8(Ni) Chem. Eur. J., 2022, 28, e202201281.
B. Mazur, F. Formalik, K. Roztocki, V. Bon, S. Kaskel, A. V. Neimark, L. Firlej, B. Kuchta Quasicontinuous Cooperative Adsorption Mechanism in Crystalline Nanoporous Materials J. Phys. Chem. Lett., 2022, 13, 30, 6961–6965
S. Haldar, M. Wang, P. Bhauriyal, A. Hazra, A. H. Khan, V. Bon, M. A. Isaacs, A. De, L. Shupletsov, T. Boenke, J. Grothe, T. Heine, E. Brunner, X. Feng, R. Dong, A. Schneemann, S. Kaskel Porous Dithiine-Linked Covalent Organic Framework as a Dynamic Platform for Covalent Polysulfide Anchoring in Lithium–Sulfur Battery Cathodes J. Am. Chem. Soc., 2022, 144, 9101–9112.
L. Bondorf, J. L. Fiorio, V. Bon, L. Zhang, M. Maliuta, S. Ehrling, I. Senkovska, J. D. Evans, J.-O. Joswig, S. Kaskel, T. Heine, M. Hirscher Isotope-selective pore opening in a flexible metal-organic framework Sci. Adv., 2022, 8, eabn7035.
S. Krause, J. D. Evans, V. Bon, S. Crespi, W. Danowski, W. R. Browne, S. Ehrling, F. Walenszus, D. Wallacher, N. Grimm, D. M. Többens, M. S. Weiss, S. Kaskel, B. L. Feringa Cooperative light-induced breathing of soft porous crystals via azobenzene buckling Nat. Commun., 2022, 13, 1-10.
K. Roztocki, F. Formalik, V. Bon, A. Krawczuk, P. Goszczycki, B. Kuchta, S. Kaskel, D. Matoga Tuning Adsorption-Induced Responsiveness of a Flexible Metal–Organic Framework JUK-8 by Linker Halogenation Chem. Mater., 2022, 34, 3430-3439.
V. Bon, N. Busov, I. Senkovska, N. Bönisch, L. Abylgazina, A. Khadiev, D. Novikov, S. Kaskel The importance of crystal size for breathing kinetics in MIL-53(Al) Chem. Commun. 2022, 58, 10492-10495.

2021

L. Gilmanova, V. Bon, L. Shupletsov, D. Pohl, M. Rauche, E. Brunner, S. Kaskel Chemically Stable Carbazole-Based Imine Covalent Organic Frameworks with Acidochromic Response for Humidity Control Applications The Journal of American Chemical Society, 2021, 143, 44, 18368–18373.
F. Walenszus, J. D. Evans, V. Bon, F. Schwotzer, I. Senkovska, S. Kaskel Integration of Fluorescent Functionality into Pressure-Amplifying Metal–Organic Frameworks Chemistry of Materials, 2021, 33, 7964−7971.
K. Roztocki, M. Rauche, V. Bon, S. Kaskel, E. Brunner, D. Matoga Combining In Situ Techniques (XRD, IR, and ¹³C NMR) and Gas Adsorption Measurements Reveals CO₂-Induced Structural Transitions and High CO₂/CH₄ Selectivity for a Flexible Metal–Organic Framework JUK-8 ACS Applied Materials & Interfaces, 2021, 13, 24, 28503–28513.
S. Ehrling, E. M. Reynolds, V. Bon, I. Senkovska, T. E. Gorelik, J.D. Evans, M. Rauche, M. Mendt, M.S. Weiss, A. Pöppl, E. Brunner, U. Kaiser, A.L. Goodwin, S. Kaskel Adaptive response of a metal–organic framework through reversible disorder–disorder transitions Nature Chemistry, 2021, 13, 568–574.
J. D. Evans, V. Bon, I. Senkovska, S. Kaskel A Universal Standard Archive File for Adsorption Data Langmuir 2021, 37, 4222–4226.
G. Jiang, V. Bon, F. Xu, B. Garai, E. Zhang, I. Senkovska, S. Poetke, F. Hippauf, S. Hausdorf, S. Paasch, E. Brunner, H. Wang, S. Kaskel A new zeolitic lithium aluminum imidazolate framework Dalton Transactions, 2021, 50, 7933-7937.
F. Schwotzer, I. Senkovska, V. Bon, S. Lochmann, J. D. Evans, D. Pohl, B. Rellinghaus, S. Kaskel Solvent-assisted delamination of layered copper dithienothiophene-dicarboxylate (DUT-134) Inorganic Chemistry Frontiers, 2021, 8, 3308-3316.
B. Felsner, V. Bon, J. D. Evans, F. Schwotzer, R. Grünker, I. Senkovska, S. Kaskel Unraveling the Guest-Induced Switchability in the Metal-Organic Framework DUT-13 (Zn) Chemistry - European Journal, 2021, 37, 9708-9715.
V. Bon, S. Krause, I. Senkovska, N. Grimm, D. Wallacher, D. M. Többens, S. Kaskel Massive pressure amplification by stimulated contraction of mesoporous frameworks Angewandte Chemie International Edition, 2021, 60, 11735-11739.
B. Garai, V. Bon, F. Walenszus, A. Khadiev, D. V. Novikov, S. Kaskel* Elucidating the Structural Evolution of a Highly Porous Responsive Metal–Organic Framework (DUT-49(M)) upon Guest Desorption by Time-Resolved in Situ Powder X-ray Diffraction Crystal Growth & Design, 2021, 21, 1, 270–276.
L. Heidari, M. Ghassemzadeh, D. Fenske, O. Fuhr, F. Mohsenzadeh, V. Bon 3D coordination polymers constructed from d¹⁰ metal ions, flexible 1,2,4-triazole derivatives and aromatic tetracarboxylates: Syntheses, structures, thermal and luminescent properties Journal of Solid State Chemistry, 2021, 296, 122011.
N. Bönisch, M. Maliuta, I. Senkovska, V. Bon, P. Petkov, C. Plätzer, P. Müller, S. Kaskel Linker Expansion and Its Impact on Switchability in Pillared-Layer MOFs Inorganic Chemistry, 2021, 60, 1726−1737.
L. Abylgazina, I. Senkovska, S. Ehrling, V. Bon, P. St. Petkov, J. D. Evans, S. Krylova, A. Krylov, S. Kaskel Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering CrystEngComm, 2021, 23, 538-549.
L. Gilmanova, R. Shekurov, M. Khrizanforov, K. Ivshin, O. Kataeva, V. Bon, I. Senkovska, S. Kaskel, V. Miluykov First example of Ugi's amine as a platform for the construction of chiral coordination polymers: synthesis and properties New Journal of Chemistry, 2021, 45, 2791-2794.
S. Krause, J. D. Evans, V. Bon, I. Senkovska, F.-X. Coudert, D. M. Többens, D. Wallacher, N. Grimm, S. Kaskel, The Role of Temperature and Adsorbate on Negative Gas Adsorption in the Mesoporous Metal-Organic Framework DUT-49. Faraday Discussions, 2021, 225, 168-183.

2020

F. Walenszus, V. Bon, J. D. Evans, S. Kaskel, M. Dvoyashkin Molecular Diffusion in a Flexible Mesoporous Metal–Organic Framework over the Course of Structural Contraction Journal of Physical Chemistry Letters, 2020, 11, 9696−9701.
B. Garai, V. Bon, A. Efimova, M. Gerlach, I. Senkovska, S. Kaskel Reversible switching between positive and negative thermal expansion in a metal-organic framework DUT-49 Journal of Materials Chemistry A, 2020, 8, 20420-20428.
S. Kintzel, K. Eckhardt, J. Getzschmann, V. Bon, J. Grothe, S. Kaskel Synthesis and Structure of the Silver(I) Complexes [Ag₂(C₄H₆O₄N)NO₃]·H₂O and Ag₆(C₆H₆O₆N)₂ for the Formulation of Silver Inks in Nanoimprint Lithography European Journal of Inorganic Chemistry, 2020, 3167–3173.
H. I. Buvailo, M. V. Pavliuk, V. G. Makhankova, V. N. Kokozay, V. Bon, E. Mijangos, S. I. Shylin, J. Jezierska Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity Inorganic Chemistry Communications, 2020, 119, 108111.
K. Roztocki, M. Szufla, V. Bon, I. Senkovska, S. Kaskel, D. Matoga Interlinker Hydrogen Bonds Govern CO₂ Adsorption in a Series of Flexible 2D Diacylhydrazone/Isophthalate-Based MOFs: Influence of Metal Center, Linker Substituent, and Activation Temperature Inorganic Chemistry, 2020, 59, 15, 10717–10726.
D. M. Polyukhov, S. Krause, V. Bon, A. S. Poryvaev, S. Kaskel, M. V. Fedin Structural Transitions of the Metal–Organic Framework DUT-49(Cu) upon Physi- and Chemisorption Studied by in Situ Electron Paramagnetic Resonance Spectroscopy Journal of Physical Chemistry Letters, 2020, 11, 15, 5856–5862.
J. D. Evans, V. Bon, I. Senkovska, H.-C. Lee, S. Kaskel Four-dimensional metal-organic frameworks Nature Communications, 2020, 11, 2690.
S. Ehrling, M. Mendt, I. Senkovska, J. D. Evans, V. Bon, P. Petkov, C. Ehrling, F. Walenszus, A. Pöppl., S. Kaskel Tailoring the Adsorption-Induced Flexibility of a Pillared Layer Metal–Organic Framework DUT-8(Ni) by Cobalt Substitution Chemistry of Materials, 2020, 32, 13, 5670–5681.
S. Krause, F. S. Reuter, S. Ehrling, V. Bon, I. Senkovska, S. Kaskel, E. Brunner Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed by In Situ ¹²⁹Xe NMR Spectroscopy Chemistry of Materials, 2020, 32, 11, 4641–4650.
K. Nguyen, S. Ehrling, I. Senkovska, V. Bon, S. Kaskel New 1D chiral Zr-MOFs based on in situ imine linker formation as catalysts for asymmetric C-C coupling reactions. Journal of Catalysis, 2020, 386, 106-116.
S. Krause, J. D. Evans, V. Bon, I. Senkovska, S. Ehrling, P. Iacomi, D. M. Többens, D. Wallacher, M. S. Weiss, B. Zheng, P. G. Yot, G. Maurin, P. L. Llewellyn, F.-X. Coudert, S. Kaskel Engineering micromechanics of soft porouscrystals for negative gas adsorption. Chemical Science, 2020, 11, 9468–9479.
P. Freund, I. Senkovska, B. Zheng, V. Bon, B. Krause, G. Maurin, S. Kaskel The force of MOFs: the potential of switchablemetal–organic frameworks as solvent stimulatedactuators Chemical Communications, 2020, 56, 7411—7414.
V. Khrizanforova; R. Shekurov; V. Miluykov; M. Khrizanforov; V. Bon; S. Kaskel; A. Gubaidullin; O. Sinyashin; Y. Budnikova, 3D Ni and Co redox-active metal–organic frameworks based on ferrocenyl diphosphinate and 4, 4′-bipyridine ligands as efficient electrocatalysts for the hydrogen evolution reaction. Dalton Transactions 2020,49, 2794-2802
V. Bon; E. Brunner; A. Pöppl; S. Kaskel, Unraveling Structure and Dynamics in Porous Frameworks via Advanced In Situ Characterization Techniques. Advanced Functional Materials 2020, 1907847.
B. Garai; V. Bon; S. Krause; F. Schwotzer; M. Gerlach; I. Senkovska; S. Kaskel, Tunable Flexibility and Porosity of the Metal–Organic Framework DUT-49 through Postsynthetic Metal Exchange. Chemistry of Materials 2020, 32 (2), 889-896.

2019

U. S. Arrozi; V. Bon; S. Krause; T. Lübken; M. S. Weiss; I. Senkovska; S. Kaskel, In Situ Imine-Based Linker Formation for the Synthesis of Zirconium MOFs: A Route to CO₂ Capture Materials and Ethylene Oligomerization Catalysts. Inorganic Chemistry 2019, 59 (1), 350-359.
U. S. Arrozi; V. Bon; C. Kutzscher; I. Senkovska; S. Kaskel, Towards highly active and stable nickel-based metal–organic frameworks as ethylene oligomerization catalysts. Dalton Transactions 2019, 48 (10), 3415-3421.
V. Bon; I. Senkovska; J. D. Evans; M. Wöllner; M. Hölzel; S. Kaskel, Insights into the water adsorption mechanism in the chemically stable zirconium-based MOF DUT-67 – a prospective material for adsorption-driven heat transformations. Journal of Materials Chemistry A 2019, 7 (20), 12681-12690.
M. E. Casco; E. Zhang; S. Grätz; S. Krause; V. Bon; D. Wallacher; N. Grimm; D. M. Többens; T. Hauß; L. Borchardt, Experimental Evidence of Confined Methane Hydrate in Hydrophilic and Hydrophobic Model Carbons. The Journal of Physical Chemistry C 2019, 123 (39), 24071-24079.
S. Ehrling; I. Senkovska; V. Bon; J. D. Evans; P. Petkov; Y. Krupskaya; V. Kataev; T. Wulf; A. Krylov; A. Vtyurin, Crystal size versus paddle wheel deformability: selective gated adsorption transitions of the switchable metal–organic frameworks DUT-8 (Co) and DUT-8 (Ni). Journal of Materials Chemistry A 2019, 7 (37), 21459-21475.
F. Kolbe; S. Krause; V. Bon; I. Senkovska; S. Kaskel; E. Brunner, High-Pressure in Situ ¹²⁹Xe NMR Spectroscopy: Insights into Switching Mechanisms of Flexible Metal–Organic Frameworks Isoreticular to DUT-49. Chemistry of Materials 2019, 31 (16), 6193-6201.
S. Krause; V. Bon; H. Du; R. E. Dunin-Borkowski; U. Stoeck; I. Senkovska; S. Kaskel, The impact of crystal size and temperature on the adsorption-induced flexibility of the Zr-based metal–organic framework DUT-98. Beilstein journal of nanotechnology 2019, 10 (1), 1737-1744.
S. Krause; J. D. Evans; V. Bon; I. Senkovska; P. Iacomi; F. Kolbe; S. Ehrling; E. Troschke; J. Getzschmann; D. M. Többens, Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks. Nature communications 2019, 10 (1), 1-12.
P. Müller; V. Bon; I. Senkovska; K. D. Nguyen; S. Kaskel, A bifunctional metal–organic framework platform for catalytic applications. Polyhedron 2019, 159, 382-386.
K. D. Nguyen; C. Kutzscher; S. Ehrling; I. Senkovska; V. Bon; M. de Oliveira Jr; T. Gutmann; G. Buntkowsky; S. Kaskel, Insights into the role of zirconium in proline functionalized metal-organic frameworks attaining high enantio-and diastereoselectivity. Journal of Catalysis 2019, 377, 41-50.
R. Shekurov; V. Khrizanforova; L. Gilmanova; M. Khrizanforov; V. Miluykov; O. Kataeva; Z. Yamaleeva; T. Burganov; T. Gerasimova; A. Khamatgalimov, Zn and Co redox active coordination polymers as efficient electrocatalysts. Dalton Transactions 2019, 48 (11), 3601-3609.
J. D. Evans, B. Garai, H. Reinsch, W. Li, S. Dissegna, V. Bon, I. Senkovska, R. A. Fischer, S. Kaskel, C. Janiak, N. Stock and D. Volkmer, Metal-organic frameworks in Germany: From synthesis to function, Coord. Chem. Rev., 2019, 380, 378-418.
P. Petkov, V. Bon, C. Hobday, A. Kuc, P. Melix, S. Kaskel, T. Düren and T. Heine, Conformational isomerism controls collective flexibility in metal-organic framework DUT-8(Ni), Physical Chemistry Chemical Physics, 2019, 21, 674-680
P. Müller, V. Bon, I. Senkovska, K. D. Nguyen, S. Kaskel, A bifunctional metal–organic framework platform for catalytic applications, 2019, 159, 382-386

2018

E. Zhang, G.-P. Hao, M. E. Casco, V. Bon, S. Graetz and L. Borchardt, Nanocasting in ball mills - combining ultra-hydrophilicity and ordered mesoporosity in carbon materials, J. Mater. Chem. A, 2018, 6, 859-865.
A. Kultaeva, V. Bon, M. S. Weiss, A. Poeppl and S. Kaskel, Elucidating the Formation and Transformation Mechanisms of the Switchable Metal-Organic Framework ELM-11 by Powder and Single-Crystal EPR Study, Inorg. Chem., 2018, 57, 11920-11929.
D. S. Krylov, F. Liu, A. Brandenburg, L. Spree, V. Bon, S. Kaskel, A. U. B. Wolter, B. Buechner, S. M. Avdoshenko and A. A. Popov, Magnetization relaxation in the single-ion magnet DySc2N@C80: quantum tunneling, magnetic dilution, and unconventional temperature dependence, Phys. Chem. Chem. Phys., 2018, 20, 11656-11672.
S. Krause, J. D. Evans, V. Bon, I. Senkovska, S. Ehrling, U. Stoeck, P. G. Yot, P. Iacomi, P. Llewellyn, G. Maurin, F.-X. Coudert and S. Kaskel, Adsorption Contraction Mechanics: Understanding Breathing Energetics in Isoreticular Metal-Organic Frameworks, J. Phys. Chem. C, 2018, 122, 19171-19179.
S. Krause, V. Bon, I. Senkovska, D. M. Toebbens, D. Wallacher, R. S. Pillai, G. Maurin and S. Kaskel, The effect of crystallite size on pressure amplification in switchable porous solids, Nat. Commun., 2018, 9, 1-8.
N. Kavoosi, T. Savchenko, I. Senkovska, M. Maliuta, V. Bon, A. Eychmueller and S. Kaskel, Selective pore opening and gating of the pillared layer metal-organic framework DUT-8(Ni) upon liquid phase multi-component adsorption, Microporous Mesoporous Mater., 2018, 271, 169-174.
I. M. Hoenicke, I. Senkovska, V. Bon, I. A. Baburin, N. Boenisch, S. Raschke, J. D. Evans and S. Kaskel, Balancing Mechanical Stability and Ultrahigh Porosity in Crystalline Framework Materials, Angew. Chem., Int. Ed., 2018, 57, 13780-13783.
F. Drache, F. G. Cirujano, K. D. Nguyen, V. Bon, I. Senkovska, F. X. Llabres i. Xamena and S. Kaskel, Anion Exchange and Catalytic Functionalization of the Zirconium-Based Metal-Organic Framework DUT-67, Cryst. Growth Des., 2018, 18, 5492-5500.

2017

S. Tomyn, S. I. Shylin, D. Bykov, V. Ksenofontov, E. Gumienna-Kontecka, V. Bon and I. O. Fritsky, Indefinitely stable iron(IV) cage complexes formed in water by air oxidation, Nat. Commun., 2017, 8, 14099.
J. Schaber, S. Krause, S. Paasch, I. Senkovska, V. Bon, D. M. Toebbens, D. Wallacher, S. Kaskel and E. Brunner, In Situ Monitoring of Unique Switching Transitions in the Pressure-Amplifying Flexible Framework Material DUT-49 by High-Pressure 129Xe NMR Spectroscopy, J. Phys. Chem. C, 2017, 121, 5195-5200.
P. Mueller, F. M. Wisser, P. Freund, V. Bon, I. Senkovska and S. Kaskel, Optical Sensors Using Solvatochromic Metal-Organic Frameworks, Inorg. Chem., 2017, 56, 14164-14169.
P. Mueller, V. Bon, I. Senkovska, J. Getzschmann, M. S. Weiss and S. Kaskel, Crystal Engineering of Phenylenebis(azanetriyl)tetrabenzoate Based Metal-Organic Frameworks for Gas Storage Applications, Cryst. Growth Des., 2017, 17, 3221-3228.
H. Miura, V. Bon, I. Senkovska, S. Ehrling, S. Watanabe, M. Ohba and S. Kaskel, Tuning the gate-opening pressure and particle size distribution of the switchable metal-organic framework DUT-8(Ni) by controlled nucleation in a micromixer, Dalton Trans., 2017, 46, 14002-14011.
C. Kutzscher, D. Janssen-Mueller, A. Notzon, U. Stoeck, V. Bon, I. Senkovska, S. Kaskel and F. Glorius, Synthesis of the homochiral metal-organic framework DUT-129 based on a chiral dicarboxylate linker with 6 stereocenters, CrystEngComm, 2017, 19, 2494-2499.
A. Krylov, A. Vtyurin, P. Petkov, I. Senkovska, M. Maliuta, V. Bon, T. Heine, S. Kaskel and E. Slyusareva, Raman spectroscopy studies of the terahertz vibrational modes of a DUT-8 (Ni) metal-organic framework, Phys. Chem. Chem. Phys., 2017, 19, 32099-32104.
S. Krause, V. Bon, U. Stoeck, I. Senkovska, D. M. Toebbens, D. Wallacher and S. Kaskel, A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design, Angew. Chem., Int. Ed., 2017, 56, 10676-10680.
N. Kavoosi, V. Bon, I. Senkovska, S. Krause, C. Atzori, F. Bonino, J. Pallmann, S. Paasch, E. Brunner and S. Kaskel, Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni), Dalton Trans., 2017, 46, 4685-4695.
W. Ju, A. Bagger, G.-P. Hao, A. S. Varela, I. Sinev, V. Bon, B. Roldan Cuenya, S. Kaskel, J. Rossmeisl and P. Strasser, Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2, Nat. Commun., 2017, 8, 1-9.
J. Fritzsche, M. Grzywa, D. Denysenko, V. Bon, I. Senkovska, S. Kaskel and D. Volkmer, CFA-4 - a fluorinated metal-organic framework with exchangeable interchannel cations, Dalton Trans., 2017, 46, 6745-6755.
F. Drache, V. Bon, I. Senkovska, J. Getzschmann and S. Kaskel, The modulator driven polymorphism of Zr(IV) based metal-organic frameworks, Philos. Trans. R. Soc., A, 2017, 375, 20160027/20160021-20160027/20160010.
V. Bon, Metal-organic frameworks for energy-related applications, Current Opinion in Green and Sustainable Chemistry, 2017, 4, 44-49.

2016

F. Drache, V. Bon, I. Senkovska, J. Getzschmann, S. Kaskel The modulator driven polymorphism of Zr(IV) based metal-organic frameworks., Phil. Trans. R. Soc. A 375 (2016): 20160027. DOI: 10.1098/rsta.2016.0027
I. Senkovska, V. Bon In situ diffraction and EXAFS methods in "The Chemistry of Metal-Organic Frameworks" (2016) ed. S. Kaskel
L. Borchardt, W. Nickel, M. Casco, I. Senkovska, V. Bon, D. Wallacher, N. Grimm, S. Krause, J. Silvestre-Albero Illuminating Solid Gas Storage in Confined Spaces - Methane Hydrate Formation in Porous Model Carbons, Phys. Chem. Chem. Phys., 18 (2016) 20607-20614; DOI:10.1039/C6CP03993F
F. Drache, V. Bon, I. Senkovska, C. Marschelke, A. Synytska, S. Kaskel Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67, Inorg. Chem., 55 (2016) 7206?7213; DOI:10.1021/acs.inorgchem.6b00829
M. Mendt, F. Gutt, N. Kavoosi, V. Bon, I. Senkovska, S. Kaskel, A. Pöppl EPR Insights into Switchable and Rigid Derivatives of the Metal-Organic Framework DUT-8(Ni) by NO Adsorption, J. Phys. Chem. C., 120(26) (2016) 14246-14259; DOI:10.1021/acs.jpcc.6b04984
F. Drache, V. Bon, I. Senkovska, M. Adam, A. Eychmüller, S. Kaskel Vapochromic Luminescence of a Zirconium-Based Metal-Organic Framework for Sensing Applications: Vapochromic Luminescence of a Zirconium-Based Metal-Organic Framework for Sensing Applications, Eur. J. Inorg. Chem., (2016) 4483-4489, DOI: 10.1002/ejic.201600261
S. Krause, V. Bon, I. Senkovska, U. Stoeck, D. Wallacher, D. M. Többens, S. Zander, R. S. Pillai, G. Maurin, F.-X. Coudert, S. Kaskel A pressure-amplifying framework material with negative gas adsorption transitions, Nature, 532 (2016) 348-352. DOI:10.1038/nature17430
C. Kutzscher, G. Nickerl, I. Senkovska, V. Bon, S. Kaskel Proline Functionalized UiO-67 and UiO-68 Type Metal-Organic Frameworks Showing Reversed Diastereoselectivity in Aldol Addition Reactions, Chem. Mater., 28(8) (2016) 2573-2580. DOI:10.1021/acs.chemmater.5b04575
V. Bon, N. Kavoosi, I. Senkovska, P. Müller, J. Schaber, D. Wallacher, D. M. Többens, U. Müller, S. Kaskel Tuning the flexibility in MOFs by SBU functionalization, Dalton Trans., 45 (2016) 4407-4415; DOI:10.1039/C5DT03504J
K. Eckhardt, V. Bon, J. Getzschmann, J. Grothe, F. M. Wisser, S. Kaskel Crystallographic insights into (CH3NH3)3(Bi2I9): A new lead-free hybrid organic-inorganic material as a potential absorber for photovoltaics, Chem. Commun., 52 (2016) 3058-3060. DOI:10.1039/C5CC10455F

2015

V. Bon, N. Kavoosi, I. Senkovska, S. Kaskel Tolerance of flexible MOFs towards repeated adsorption stress ACS Appl. Mater. Interfaces, 7 (2015) 22292–22300. DOI:10.1021/acsami.5b05456
V. Bon, N. Klein, I. Senkovska, A. Heerwig, J. Getzschmann, D. Wallacher, I. Zizak, M. Brzhezinskaya, U. Mueller, S. Kaskel Exceptional adsorption-induced cluster and network deformation in the flexible metal-organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS Phys. Chem. Chem. Phys., 17 (2015) 17471-17479; DOI:10.1039/C5CP02180D
S. Helten, B. Sahoo, P. Müller, D. Janßen-Müller, N. Klein, R. Grünker, V. Bon, F. Glorius, S. Kaskel, I. Senkovska Functional group tolerance in BTB-based metal–organic frameworks (BTB – benzene-1,3,5-tribenzoate), Microporous Mesoporous Mater., 216 (2015) 42-50; DOI:10.1016/j.micromeso.2015.02.055
P. Müller, F. M. Wisser, V. Bon, R. Grünker, I. Senkovska, S. Kaskel Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(azanetriyl)tetrabenzoate-Based MOFs, Chem. Mater., 27 (2015) 2460 - 2467. DOI:10.1021/cm5045732
V. Bon, J. Pallmann, E. Eisbein, H. C. Hoffmann, I. Senkovska, I. Schwedler, A. Schneemann, S. Henke, D. Wallacher, R. A. Fischer, G. Seifert, E. Brunner, S. Kaskel, Characteristics of flexibility in metal-organic framework solid solutions of composition [Zn2(BME-bdc)x(DB-bdc)2-xdabco]n: In situ powder X-ray diffraction, in situ NMR spectroscopy, and molecular dynamics simulations, Microporous Mesoporous Mater., 216 (2015) 64-74. DOI:10.1016/j.micromeso.2015.02.042
U. Stoeck, I. Senkovska, V. Bon, S. Krause, S. Kaskel Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery, Chem. Commun., 51 (2015) 1046-1049; DOI:10.1039/c4cc07920e
S. Helten, B. Sahoo, V. Bon, I. Senkovska, S. Kaskel, F. Glorius Copolymerisation at work: The first example of a highly porous MOF comprising a triarylborane-based linker, CrystEngComm, 17 (2015) 307-312; DOI:10.1039/C4CE01400F

2014

E. Keceli, M. Hemgesberg, R. Grünker, V. Bon, C. Wilhelm, T. Philippi, R. Schoch, Y. Sun, M. Bauer, S. Ernst, S. Kaskel, Werner R. Thiel A series of amide functionalized isoreticular metal organic frameworks, Microporous Mesoporous Mater., 194 (2014) 115–125; DOI:10.1016/j.micromeso.2014.03.022
A. Schneemann, V. Bon, I. Schwedler, I. Senkovska, S. Kaskel, R. A. Fischer Flexible metal-organic frameworks, Chem. Soc. Rev., 43 (2014) 6062-6096; DOI:10.1039/c4cs00101j
G. Nickerl, M. Leistner, S. Helten, V. Bon, I. Senkovska, S. Kaskel Integration of Accessible Secondary Metal Sites into MOFs for H2S Removal, Inorg. Chem. Front., 1 (2014) 325-330; DOI:10.1039/C3QI00093A
V. Bon, I. Senkovska, D. Wallacher, A. Heerwig, N. Klein, I. Zizak, R. Feyerherm, E. Dudzik, S. Kaskel, In situ monitoring of structural changes during the adsorption on flexible porous coordination polymers by X-ray powder diffraction: Instrumentation and experimental results, Microporous Mesoporous Mater., 188 (2014) 190–195; DOI:10.1016/j.micromeso.2013.12.024
R. Grünker, V. Bon, P. Müller, U. Stoeck, S. Krause, U. Mueller, I. Senkovska, S. Kaskel, A new metal-organic framework with ultra-high surface area, Chem. Commun., 50 (2014) 3450-3452. DOI:10.1039/c4cc00113c
V. Bon, I. Senkovska, D. Wallacher, D. M Többens, I. Zizak, R. Feyerherm, U. Mueller, S. Kaskel In Situ Observation of Gating Phenomena in the Flexible Porous Coordination Polymer Zn-2(BPnDC)2(bpy) (SNU-9) in a Combined Diffraction and Gas Adsorption Experiment, Inorg. Chem., 53 (2014) 1513–1520; DOI:10.1021/ic4024844

2012...2011

R. Grünker, V. Bon, A. Heerwig, N. Klein, P. Müller, U. Stoeck, I. A Baburin, U. Mueller, I. Senkovska, S. Kaskel Dye Encapsulation Inside a New Mesoporous Metal-Organic Framework for Multifunctional Solvatochromic-Response Function, Chem. Eur. J., 18 (2012) 13299-13303; DOI:10.1002/chem.201202352
U. Stoeck, S. Krause, V. Bon, I. Senkovska, S. Kaskel A highly porous metal-organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake, Chem. Commun., 48 (2012) 10841-10843; DOI:10.1039/c2cc34840c
L. Schlechte, V. Bon, R. Grünker, N. Klein, I. Senkovska, S. Kaskel Reprint of “Structural diversity of cobalt(II) coordination compounds involving bent imidazole ligand: A route from 0D dimer to 3D coordination polymer” Polyhedron, 44 (2012) 179–186; DOI:10.1016/j.poly.2012.06.065
V. Bon, V. Senkovskyy, I. Senkovska, S. Kaskel Mesoporous Zr IV and Hf IV metal–organic frameworks with reo topology, Acta Cryst. A, 68 (2012) s225. DOI:10.1107/S0108767312095645
V. Bon, V. Senkovskyy, I. Senkovska, S. Kaskel Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology, Chem. Commun., 48 (2012) 8407-8409; DOI:10.1039/c2cc34246d
I. M. Hauptvogel, V. Bon, R. Grünker, I. A Baburin, I. Senkovska, U. Mueller, S. Kaskel A family of 2D and 3D coordination polymers involving a trigonal tritopic linker, Dalton Trans. 41 (2012) 4172-4179; DOI:10.1039/c2dt12072k
I. M. Hauptvogel, V. Bon, R. Grünker, I. A Baburin, I. Senkovska, U. Mueller, S. Kaskel A family of 2D and 3D coordination polymers involving a trigonal tritopic linker, Dalton Trans. 41 (2012) 4172-4179; DOI:10.1039/c2dt12072k
M. Padmanaban, P. Müller, C. Lieder, K. Gedrich, R. Grünker, V. Bon, I. Senkovska, S. Baumgärtner, S. Opelt, S. Paasch, E. Brunner, F. Glorius, E. Klemm, S. Kaskel Application of a chiral metal-organic framework in enantioselective separation, Chem. Commun., 47 (2011) 12089-12091; DOI:10.1039/c1cc14893a